Syngas Production from Ethanol Dry Reforming over Cu/Ce0.8Zr0.2O2 Catalyst

被引：20

作者：

Cao, Dong ^{[1
]}

Cai, Weijie ^{[1
,3
]}

Li, Yi ^{[2
]}

Li, Congming ^{[3
]}

Yu, Hao ^{[4
]}

Zhang, Shaoyin ^{[1
]}

Qu, Fengzuo ^{[1
]}

机构：

[1] Dalian Polytech Univ, Fac Light Ind & Chem Engn, Dalian 116023, Peoples R China

[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

[3] Taiyuan Univ Technol, State Key Lab Breeding Base Coal Sci & Technol, Taiyuan 030024, Shanxi, Peoples R China

[4] Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China

来源：

CATALYSIS LETTERS | 2017年 / 147卷 / 12期

关键词：

Cu/Ce0.8Zr0.2O2; Ethanol dry reforming; Syngas; Hydrogen; CO OXIDATION ACTIVITY; HYDROGEN-PRODUCTION; LOW-TEMPERATURE; MIXED OXIDES; CE; CU; ZR; METHANE; CERIA; IMPREGNATION;

D O I：

10.1007/s10562-017-2216-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Cu/Ce0.8Zr0.2O2 catalyst was synthesized by facile co-precipitation method and deeply studied for syngas production from carbon dioxide reforming of ethanol at various temperature and reactant ratios. The investigated catalyst showed promising activity and excellent stability along 90 h test, which was assigned to the strong synergistic metal-support interaction and high redox capacity as revealed by different characterization technique including X-ray diffraction (XRD), Raman, Oxygen storage capacity (OSC) and Temperature programmed reduction (H-2-TPR) etc. [GRAPHICS]

引用

页码：2929 / 2939

页数：11

共 64 条

[1] Performance of Nickel Supported on γ-Alumina Obtained by Aluminum Recycling for Methane Dry Reforming [J].

Adans, Ysla Franca ;

Ballarini, Adriana Daniela ;

Martins, Andre Rosa ;

Coelho, Rodrigo Estevam ;

Carvalho, Luciene Santos .

CATALYSIS LETTERS, 2017, 147 (08) :2057-2066

[2] The CO2-CeO2 interaction and its role in the CeO2 reactivity [J].

Appel, LG ;

Eon, JG ;

Schmal, M .

CATALYSIS LETTERS, 1998, 56 (04) :199-202

[3] Ethanol dry reforming for syngas production over Ce-promoted Ni/Al2O3 catalyst [J].

Bahari, Mahadi B. ;

Nguyen Huu Huy Phuc ;

Abdullah, Bawadi ;

Alenazey, Feraih ;

Vo, Dai-Viet N. .

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2016, 4 (04) :4830-4838

[4] Hydrogen-rich Syngas Production from Ethanol Dry Reforming on La-doped Ni/Al2O3 Catalysts: Effect of promoter loading [J].

Bahari, Mahadi B. ;

Goo, Boon Chin ;

Pham, Thong L. M. ;

Siang, Tan Ji ;

Danh, Huong T. ;

Ainirazali, Nurul ;

Vo, Dai-Viet N. .

PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 :654-661

[5] Carbon dioxide reforming of ethanol over Ni/Y2O3-ZrO2 catalysts [J].

Bellido, Jorge D. A. ;

Tanabe, Eurico Y. ;

Assaf, Elisabete M. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 90 (3-4) :485-488

[6] Structural investigation of combustion synthesized Cu/CeO2 catalysts by EXAFS and other physical techniques:: Formation of a Ce1-xCuxO2-δ solid solution [J].

Bera, P ;

Priolkar, KR ;

Sarode, PR ;

Hegde, MS ;

Emura, S ;

Kumashiro, R ;

Lalla, NP .

CHEMISTRY OF MATERIALS, 2002, 14 (08) :3591-3601

[7] Ethanol steam reforming over Rh/CexZr1-xO2 catalysts:: Impact of the CO-CO2-CH4 interconversion reactions on the H2 production [J].

Birot, Anne ;

Epron, Florence ;

Descorme, Claude ;

Duprez, Daniel .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 79 (1-2) :17-25

[8] CO2 capture by calcium aluminate pellets in a small fluidized bed [J].

Blamey, John ;

Al-Jeboori, Mohamad J. ;

Manovic, Vasilije ;

Fennell, Paul S. ;

Anthony, Edward J. .

FUEL PROCESSING TECHNOLOGY, 2016, 142 :100-106

[9] Methanol Synthesis from Industrial CO2 Sources: A Contribution to Chemical Energy Conversion [J].

Bukhtiyarova, Marina ;

Lunkenbein, Thomas ;

Kaehler, Kevin ;

Schloegl, Robert .

CATALYSIS LETTERS, 2017, 147 (02) :416-427

[10] Hydrogen production from ethanol over Ir/CeO2 catalysts:: A comparative study of steam reforming, partial oxidation and oxidative steam reforming [J].

Cai, Weijie ;

Wang, Fagen ;

Zhan, Ensheng ;

Van Veen, A. C. ;

Mirodatos, Claude ;

Shen, Wenjie .

JOURNAL OF CATALYSIS, 2008, 257 (01) :96-107

← 1 2 3 4 5 6 7 →