Covalent binding of a nickel macrocyclic complex to a silica support: towards an electron exchange column

被引：9

作者：

Attia, Smadar ^{[1
]}

Shames, Alexander ^{[2
]}

Zilbermann, Israel ^{[1
,4
]}

Goobes, Gil ^{[3
]}

Maimon, Eric ^{[1
,4
]}

Meyerstein, Dan ^{[1
,5
]}

机构：

[1] Ben Gurion Univ Negev, Dept Chem, Beer Sheva, Israel

[2] Ben Gurion Univ Negev, Dept Phys, IL-84105 Beer Sheva, Israel

[3] Bar Ilan Univ, Dept Chem, Ramat Gan, Israel

[4] Nucl Res Ctr Negev, Dept Chem, IL-84190 Beer Sheva, Israel

[5] Ariel Univ, Dept Biol Chem, Ariel, Israel

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 01期

关键词：

SOL-GEL MATERIALS; GRAFTED MESOPOROUS SILICA; AQUEOUS-SOLUTIONS; PULSE-RADIOLYSIS; ELECTROCATALYTIC REDUCTION; STATIONARY PHASES; CRYSTAL-STRUCTURE; REDOX CHEMISTRY; OXIDATION; PERCHLORATE;

D O I：

10.1039/c3dt51962g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ni(II) L-2, L-2 = 1-propyl-1,3,5,8,12-pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(III) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

引用

页码：103 / 110

页数：8

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