Epitaxies of Ca sulfates on calcite. II. The main {010}, {001} and {100} forms of bassanite epideposited on the {10.4} substrate form of calcite

被引:4
作者
Aquilano, Dino [1 ]
Bruno, Marco [1 ,2 ,3 ]
Ghignone, Stefano [1 ]
Pastero, Linda [1 ,2 ,3 ]
Cotellucci, Andrea [1 ]
机构
[1] Univ Torino, Dipartimento Sci Terra, Via Valperga Caluso 35, I-10125 Turin, Italy
[2] Univ Torino, Spin Off Acad, SpectraLab Srl, Via G Quarello 15-A, I-10135 Turin, Italy
[3] Univ Torino, NIS, Ctr Nanostruct Interfaces & Surfaces, Via G Quarello 15-A, I-10135 Turin, Italy
关键词
bassanite; calcite; epitaxy; twins; anomalous mixed crystals; HEMIHYDRATE; STATOLITHS; CRYSTALS;
D O I
10.1107/S1600576722008196
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2D and 3D epitaxies of the main {010}, {001} and {100} forms of deposited bassanite (CaSO(4)(.)0.5H(2)O) on {10.4} calcite (CaCO3) as a substrate are described to provide a theoretical crystallographic background for the replacement of calcite by bassanite both in nature and in the laboratory and by weathering linked to cultural heritage. First, epitaxy in the third dimension, perpendicular to the investigated interfaces, has been verified in order to establish whether adsorption/absorption can occur (as anomalous mixed crystals) at the bassanite/ calcite epi-contacts. Secondly, and by applying the Hartman-Perdok method, 2D lattice coincidences have been obtained from the physical-geometric matches of bonds running in the common directions within the elementary slices facing the substrate/deposit interfaces. This research represents the second and more detailed part of a wider program extended to the epi-interactions between the following pairs: (i) {010}-gypsum/{10.4}-calcite (just published); (ii) bassanite/ {10.4}-calcite (the present work); and (iii) anhydrite (CaSO4)/{10.4}-calcite (coming soon).
引用
收藏
页码:1289 / 1296
页数:8
相关论文
共 15 条
[1]   Epitaxies of Ca-sulfates on calcite (CaCO3) I. Gypsum {010} on the calcite {10.4} form: epi-twins of gypsum induced by the calcite substrate [J].
Aquilano, D. ;
Bruno, M. ;
Cotellucci, A. ;
Pastero, L. ;
Ghignone, S. .
CRYSTENGCOMM, 2022, 24 (28) :5120-5127
[2]   THEORETICAL EQUILIBRIUM AND GROWTH-MORPHOLOGY OF ANHYDRITE (CASO4) CRYSTALS [J].
AQUILANO, D ;
RUBBO, M ;
CATTI, M ;
PAVESE, A ;
UGLIENGO, P .
JOURNAL OF CRYSTAL GROWTH, 1992, 125 (3-4) :519-532
[3]   COMPLEX GROWTH POLYTYPISM AND PERIODIC POLYSYNTHETIC TWINS ON OCTACOSANE CRYSTALS (N-C28H58) [J].
AQUILANO, D .
JOURNAL OF CRYSTAL GROWTH, 1977, 37 (03) :215-228
[4]   The monoclinic I2 structure of bassanite, calcium sulphate hemihydrate (CaSO4 • 0.5H2O) [J].
Ballirano, P ;
Maras, A ;
Meloni, S ;
Caminiti, R .
EUROPEAN JOURNAL OF MINERALOGY, 2001, 13 (05) :985-993
[5]   Calcium sulfate hemihydrate is the inorganic mineral in statoliths of Scyphozoan medusae (Cnidaria) [J].
Becker, A ;
Sötje, I ;
Paulmann, C ;
Beckmann, F ;
Donath, T ;
Boese, R ;
Prymak, O ;
Tiemann, H ;
Epple, M .
DALTON TRANSACTIONS, 2005, (08) :1545-1550
[6]   INTERACTION ENERGY AND GROWTH MECHANISMS ON TWINNED AND POLYTYPIC CRYSTALS OF LONG-CHAIN EVEN NORMAL-ALKANES .1. INTERACTION-ENERGY CALCULATIONS [J].
BOISTELLE, R ;
AQUILANO, D .
ACTA CRYSTALLOGRAPHICA SECTION A, 1977, 33 (JUL1) :642-648
[7]  
Hartman P., 1973, Crystal Growth: an Introduction
[8]   Electron Backscatter Diffraction (EBSD) Analysis of Bassanite Transformation Textures and Crystal Structure Produced from Experimentally Deformed and Dehydrated Gypsum [J].
Hildyard, Rebecca C. ;
Llana-Funez, Sergio ;
Wheeler, John ;
Faulkner, Daniel R. ;
Prior, David J. .
JOURNAL OF PETROLOGY, 2011, 52 (05) :839-856
[9]   A Fast and Sustainable Route to Bassanite Nanocrystals from Gypsum [J].
Maslyk, Marcel ;
Dallos, Zsolt ;
Koziol, Martha ;
Seiffert, Sebastian ;
Hieke, Tim ;
Petrovio, Katharina ;
Kolb, Ute ;
Mondeshki, Mihail ;
Tremel, Wolfgang .
ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (20)
[10]   Experimental study of the replacement of calcite by calcium sulphates [J].
Ruiz-Agudo, E. ;
Putnis, C. V. ;
Hoevelmann, J. ;
Alvarez-Lloret, P. ;
Ibanez-Velasco, A. ;
Putnis, A. .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2015, 156 :75-93