Bio-inspired self-assembled molecular capsules

被引：7

作者：

Satha, Pardhasaradhi ^{[1
]}

Illa, Giriteja ^{[1
]}

Ghosh, Arindam ^{[1
]}

Purohit, Chandra Shekhar ^{[1
]}

机构：

[1] Natl Inst Sci Educ & Res, Bhubaneswar 751005, Odisha, India

来源：

RSC ADVANCES | 2015年 / 5卷 / 91期

关键词：

DIELS-ALDER REACTION; METAL-IONS; RECOGNITION; ENCAPSULATION; DIFFUSION; LIGANDS; ADENINE; NUCLEOBASES; DERIVATIVES; ENTRAPMENT;

D O I：

10.1039/c5ra16421d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bowl shaped molecules are useful for making molecular capsules with suitable non-covalent bonds. Bowl shaped cyclotriguaiacylene can be suitably modified at its phenolic groups for attaching suitable functionality to construct molecular capsules. In this work, a molecular capsule has been prepared by appending adenine and thymine to cyclotriguaiacylene. These blocks when mixed in a mixture of solvents give a molecular capsule as ascertained by mass and NMR spectroscopy.

引用

页码：74457 / 74462

页数：6

共 59 条

[1] A highly symmetric diamond-like assembly of cyclotricatechylene-based tetrahedral cages [J].

Abrahams, Brendan F. ;

Boughton, Berin A. ;

FitzGerald, Nicholas J. ;

Holmes, Jessica L. ;

Robson, Richard .

CHEMICAL COMMUNICATIONS, 2011, 47 (26) :7404-7406

[2] Cages with Tetrahedron-Like Topology Formed from the Combination of Cyclotricatechylene Ligands with Metal Cations [J].

Abrahams, Brendan F. ;

Fitzgerald, Nicholas J. ;

Robson, Richard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (16) :2896-2899

[3] Closed and Open Clamlike Structures Formed by Hydrogen-Bonded Pairs of Cyclotricatechylene Anions that Contain Cationic "Meat" [J].

Abrahams, Brendan F. ;

FitzGerald, Nicholas J. ;

Hudson, Timothy A. ;

Robson, Richard ;

Waters, Tom .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (17) :3129-3132

[4] Tuning MOF CO2 Adsorption Properties via Cation Exchange [J].

An, Jihyun ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5578-+

[5] Cation-Triggered Drug Release from a Porous Zinc-Adeninate Metal-Organic Framework [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8376-+

[6] MOLECULAR RECOGNITION WITH CONVERGENT FUNCTIONAL-GROUPS .6. SYNTHETIC AND STRUCTURAL STUDIES WITH A MODEL RECEPTOR FOR NUCLEIC-ACID COMPONENTS [J].

ASKEW, B ;

BALLESTER, P ;

BUHR, C ;

JEONG, KS ;

JONES, S ;

PARRIS, K ;

WILLIAMS, K ;

REBEK, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (03) :1082-1090

[7] Diffusion measurements for molecular capsules: Pulse sequences effect on water signal decay [J].

Avram, L ;

Cohen, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (15) :5714-5719

[8] Calixarene-based multivalent ligands [J].

Baldini, L. ;

Casnati, A. ;

Sansone, F. ;

Ungaro, R. .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) :254-266

[9] Improved synthesis of functional CTVs and cryptophanes using Sc(OTf)3 as catalyst [J].

Brotin, T ;

Roy, V ;

Dutasta, JP .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (16) :6187-6195

[10] SYNTHESIS AND EXCITON OPTICAL-ACTIVITY OF D3-CRYPTOPHANES [J].

CANCEILL, J ;

COLLET, A ;

GOTTARELLI, G ;

PALMIERI, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) :6454-6464

← 1 2 3 4 5 6 →