Conversion of primary amines into secondary amines on a metal-organic framework using a tandem post-synthetic modification

被引：16

作者：

Burrows, Andrew D. ^{[1
]}

Keenan, Luke L. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 12期

关键词：

POSTSYNTHETIC MODIFICATION; COVALENT MODIFICATION; FUNCTIONALIZATION; REACTIVITY; TOPOLOGY; MOFS;

D O I：

10.1039/c2ce25131k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The amine-functionalised metal-organic framework (MOF) [Zn4O(bdc-NH2)(3)] (IRMOF-3, bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) has been post-synthetically modified in a tandem condensation-reduction process into secondary amine-containing MOFs. The degree of modification is enhanced by introduction of methanol, which helps to remove boron-containing side-products from the pores.

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收藏

页码：4112 / 4114

页数：3

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