Utilizing of 2-Amino-3-hydroxypyridine Modified Glassy Carbon Electrode to Detect Copper(II) Ions

被引:0
作者
Mulazimoglu, Aysen Demir [1 ]
机构
[1] Necmettin Erbakan Univ, Ahmet Kelesoglu Educ Fac, Dept Chem, TR-42090 Konya, Turkey
关键词
2-Amino-3-hydroxypyridine; Sensor electrode; Copper(II) ions; Surface modification; Surface characterization; ELECTROCATALYTIC HYDROGENATION; COVALENT MODIFICATION; SURFACES;
D O I
10.14233/ajchem.2013.14393
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper 2-amino-3-hydroxypyridine modified glassy carbon electrode was used for the electrochemical analysis of trace copper(II) ions by square wave voltammetry technique. The modification of the glassy carbon electrode by 2-amino-3-hydroxypyridine soution was performed in the potential range between -150 mV and +600 mV by 30 cycles at 100 mV s(-1) potential scan rate in non-aqueous media by cyclic voltammetry. The surface characterizations of this sensor electrode were performed by cyclic voltammetry. A lower detection limit would be reached in the presence of Britton-Robinson buffer solutin at pH 5 for determination of Cu(II) ions by square wave voltammetry. The voltammetric response of the electrode was linear within the Ci(II) ion concentration range from 1.0 x 10(-12) M to 1.0 x 10(-6) M and the detection limit of 1.0 x 10(-12) M. The modified electrode offered and excellent way, with a high stability, simple, rapid, low cost and reusability, for selective determination of Cu(II) ions in Acigol lake (in Afyonkarahisar, Turkey) water sample.
引用
收藏
页码:3491 / 3494
页数:4
相关论文
共 16 条
  • [1] Covalent modification of carbon surfaces by aryl radicals generated from the electrochemical reduction of diazonium salts
    Allongue, P
    Delamar, M
    Desbat, B
    Fagebaume, O
    Hitmi, R
    Pinson, J
    Saveant, JM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (01) : 201 - 207
  • [2] Derivatization of carbon surfaces by anodic oxidation of arylacetates. Electrochemical manipulation of the grafted films
    Andrieux, CP
    Gonzalez, F
    Saveant, JM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (18) : 4292 - 4300
  • [3] Downard AJ, 2000, ELECTROANAL, V12, P1085, DOI 10.1002/1521-4109(200010)12:14<1085::AID-ELAN1085>3.0.CO
  • [4] 2-A
  • [5] Simultaneous determination of copper, lead and cadmium by cathodic adsorptive stripping voltammetry using artificial neural network
    Ensafi, AA
    Khayamian, T
    Benvidi, A
    Mirmomtaz, E
    [J]. ANALYTICA CHIMICA ACTA, 2006, 561 (1-2) : 225 - 232
  • [6] McCreery RL, 1999, INTERFACIAL ELECTROCHEMISTRY, P631
  • [7] Mulazimoglu A.D., 2012, FOOD ANAL METHOD, DOI [10.1007/s12161-012-9492-5, DOI 10.1007/S12161-012-9492-5]
  • [8] Electrochemical Properties of MDA/GC Electrode and Investigation of Usability as Sensor Electrode for Determination of Que, Kae, Lut and Gal Using CV, DPV and SWV
    Mulazimoglu, Aysen Demir
    Mulazimoglu, Ibrahim Ender
    [J]. FOOD ANALYTICAL METHODS, 2013, 6 (01) : 141 - 147
  • [9] Determination of copper ions based on newly developed poly-chrysin modified glassy carbon sensor electrode
    Mulazimoglu, Aysen Demir
    Mulazimoglu, Ibrahim Ender
    Yilmaz, Ecir
    [J]. REVIEWS IN ANALYTICAL CHEMISTRY, 2012, 31 (02) : 131 - 137
  • [10] A novel apigenin modified glassy carbon sensor electrode for the determination of copper ions in soil samples
    Mulazimoglu, Ibrahim Ender
    Solak, Ali Osman
    [J]. ANALYTICAL METHODS, 2011, 3 (11) : 2534 - 2539