In situ hydrogen generation from cycloalkanes using a Pt/CNF catalyst

被引：47
作者：
Lazaro, M. P. [1 ]
Garcia-Bordeje, E. [1 ]
Sebastian, D. [1 ]
Lazaro, M. J. [1 ]
Moliner, R. [1 ]
机构：
[1] CSIC, Inst Carboquim, Zaragoza 50018, Spain
来源：
CATALYSIS TODAY | 2008年 / 138卷 / 3-4期
关键词：
Pt catalyst; Carbon nanofibers; Hydrogen production; Decalin;
D O I：
10.1016/j.cattod.2008.05.011
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Pt catalyst supported on carbon nanofibers (CNFs) has been prepared via ion-exchange and it was characterized by XRD, TEM, N-2 physisorption and CO chemisorption. The Pt/CNF catalyst has a small Pt crystallite size in the range of 2-3 nm. This catalyst has been tested in the dehydrogenation of decalin, which is a cycloalkane proposed in the literature as H-2 storage media for vehicles and portable devices. The objective is finding a Pt catalyst suitable for in situ generation of H-2 from chemical storage in decalin. The results revealed that Pt supported on CNF outperforms a Pt catalyst supported on micro-mesoporous activated carbon. Finally, we propose a reactor configuration aiming at the intensification of H 2 production in continuous. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：203 / 209
页数：7
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