Preparation of Pd/MnO2-reduced graphene oxide nanocomposite for methanol electro-oxidation in alkaline media

被引:82
作者
Liu, Rui [1 ,2 ]
Zhou, Haihui [1 ,2 ]
Liu, Jia [1 ,2 ]
Yao, Yuan [3 ]
Huang, Zhongyuan [1 ,2 ]
Fu, Chaopeng [1 ,2 ]
Kuang, Yafei [1 ,2 ]
机构
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China
[2] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China
[3] Harbin Inst Technol, Sch Marine Sci & Technol, Weihai 264209, Peoples R China
基金
中国国家自然科学基金;
关键词
Graphene; MnO2; Pd nanoparticles; Methanol oxidation; CARBON NANOTUBES; ETHANOL ELECTROOXIDATION; NANOPARTICLES; CATALYSTS; COMPOSITES; OXIDATION; PT/C;
D O I
10.1016/j.elecom.2012.10.019
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Manganese dioxide modified reduced graphene oxide supported Pd nanoparticles (Pd/MnO2-RGO) were prepared facilely by a chemical approach. The as-prepared materials were characterized by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrocatalytic behavior of the Pd/MnO2-RGO for methanol oxidation was studied using cyclic voltammetry and chronoamperometry. The results indicate that the Pd/MnO2-RGO nanocomposites exhibit higher catalytic activity and better stability than Pd/RGO. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:63 / 66
页数:4
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