Surface treatment of zinc coatings by molybdate solutions

被引:23
作者
Fachikov, L. [1 ]
Ivanova, D. [1 ]
机构
[1] Univ Chem Technol & Met, BU-1756 Sofia, Bulgaria
关键词
Zinc coatings; Non-chromate treatment; Molybdate treatment; CONVERSION COATINGS; PASSIVATION; ALLOYS;
D O I
10.1016/j.apsusc.2012.06.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of different factors such as concentration, temperature, pH and cathodic polarization on formation, properties and composition of coatings obtained under treatment of zinc surfaces by molybdate solutions has been investigated by gravimetric, electrochemical and physical methods. Coatings obtained at pH 4 are distinguished for the best uniformity and density of color. The thicknesses of coatings raise by increasing the cathode current density under other equal conditions. Molybdenum, zinc and phosphorus are the basic components of the passive films. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:10160 / 10167
页数:8
相关论文
共 16 条
[1]  
BRIGGS D, 1983, PRACTICAL SURFACE AN, pCH1
[2]  
Cowieson D. R., 1986, P IMF ANN C 17 MAY, P119
[3]  
Cowieson DR., 1985, Transactions of the IMF, DOI [10.1080/00202967.1985.11870707, DOI 10.1080/00202967.1985.11870707]
[4]   Electrochemical determination of corrosion protection properties of chromated zinc, zinc alloy and cadmium electroplated coatings [J].
Dobrev, T ;
Monev, M ;
Krastev, I ;
Richtering, W ;
Zlatev, R ;
Rashkov, S .
TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 1996, 74 :45-50
[5]  
Dobrev Ts., 1995, Bulgaria Patent, Registration No, Patent No. 99469
[6]  
KEPING H, 1996, T I MET FINISH, V74, P36
[7]   Synthesis and evaluation of corrosion resistance of molybdate-based conversion coatings on electroplated zinc [J].
Liu, Dian-long ;
Yang, Zhi-gang ;
Wang, Zhen-qiang ;
Zhang, Chi .
SURFACE & COATINGS TECHNOLOGY, 2010, 205 (07) :2328-2334
[8]  
Roman, 1996, T I MET FINISH, V74, P171
[9]  
Schweikher E. W., US Patent, Patent No. [2, 351, 639, 2351639]
[10]  
Steel Kobe, UK Patent Application, Patent No. [GB 2, 070, 073, 2070073]