Hydrothermal Synthesis and Crystal Structure of Ni(II) and Co(II) Complexes with Hydrazone Ligand

被引：0

作者：

Zheng Chang-Zheng ^{[1
]}

Wang Liang ^{[1
]}

Liu Juan ^{[1
]}

机构：

[1] Xian Polytech Univ, Sch Environm & Chem Engn, Xian 710048, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 28卷 / 03期

关键词：

Schiff base; hydrazone ligand; hydrothermal synthesis; complexes; crystal structure; COPPER(II) COMPLEXES; CU-II;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new bidentate ON hydrazone ligand, has been designed and synthesized by benzylidene acetophenone with benzoyl hydrazine (Hbabh). Two coordination compounds, namely [M(babh)(2)(py)(2)] (M=Ni, 1; Co, 2; Hbabh=benzylidene acetophenone benzoyl hydrazone, py=pyridine), have been hydrotherrnally synthesized and characterized by analytical, IR, TG analysis and single-crystal X-ray diffraction measurements. The two compounds crystallize in the Monoclinic space group P2(1)/n. A view of 2D sheet structure in 1 and 2 are packed alongside with each other through weak C-H center dot center dot center dot pi interactions. CCDC: 819582, 1; 819583, 2.

引用

页码：637 / 642

页数：6

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