Polyimido uranium(IV) clusters:: Imidometalates with an M7(μ3-N)6(μ2-N)6 core analogous to the Anderson-type polyoxometalate motif

被引：24

作者：

Berthet, Jean-Claude ^{[1
]}

Thuery, Pierre ^{[1
]}

Ephritikhine, Michel ^{[1
]}

机构：

[1] CEA Saclay, Serv Chim Mol, DSM, IRAMIS,CNRS URA 331, F-91191 Gif Sur Yvette, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 30期

关键词：

actinides; cluster compounds; imides; structure elucidation; uranium;

D O I：

10.1002/anie.200801420

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) NU clusters: Novel imido uranium(IV) clusters involving four or seven metal centers have been obtained from the reaction of UCl 4 and [{PhNMg(thf)}6] in thf or pyridine (see core structure; U yellow, N purple, Cl green, O red). The aggregation is strongly dependent on the nature of the solvent. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5586 / 5589

页数：4

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