Spin trapping with phosphonothionesters. Part VI. Phosphoryl- and thiophosphoryl-thionformates

被引：6
作者：
Alberti, A
Benaglia, M
Hudson, A
Macciantelli, D
Masson, S
机构：
[1] CNR, Area Ric, ICoCEA, I-40129 Bologna, Italy
[2] Ismra Univ, UMR 6507, Lab Chim Mol & Thio Organ, F-1450 Caen, France
[3] Shelleys Barn, Uckfield TN22 3XB, E Sussex, England
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2001年 / 27卷 / 06期
关键词：
D O I：
10.1163/156856701317051752
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate. ethyl (diethoxyphosphoryl)(thiolformate, and ethyl (die thoxythiophosphorl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters even the former compounds, however. exhibited a remarkably lower reactivity than similarly substituted dithioesters.
引用
收藏
页码：659 / 668
页数：10
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