Catalytic activation of nitrogen derivatives with transition-metal complexes

被引：59
|
作者：
Lebel, H [1 ]
Leogane, O [1 ]
Huard, K [1 ]
Lectard, S [1 ]
机构：
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
PURE AND APPLIED CHEMISTRY | 2006年 / 78卷 / 02期
关键词：
Curtius rearrangement; nitrene; aziridination; C-H insertion; rhodium;
D O I：
10.1351/pac200678020363
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Studies regarding the transition-metal-catalyzed decomposition of nitrogen derivatives toward Curtius rearrangement and the formation of nitrenes which undergo C-H insertion and aziridination reactions are presented. These processes lead to the formation of C-N bond with a high level of selectivity and efficiency.
引用
收藏
页码：363 / 375
页数：13
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