Photoinduced 1,2,3,4-tetrahydropyridine ring conversions

被引：2

作者：

Turovska, Baiba ^{[1
]}

Lund, Henning ^{[2
]}

Lusis, Viesturs ^{[1
]}

Lielpetere, Anna ^{[1
]}

Liepins, Edvards ^{[1
]}

Beljakovs, Sergejs ^{[1
]}

Goba, Inguna ^{[1
]}

Stradins, Janis ^{[1
]}

机构：

[1] Latvian Inst Organ Synth, Phys Organ Chem Lab, LV-1006 Riga, Latvia

[2] Aarhus Univ, Dept Organ Chem, DK-8000 Aarhus, Denmark

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 11卷

关键词：

heterocyclic hydroperoxide; oxaziridine; photoinduced electron transfer; pyrrolidine; tetrahydropyridine; SUPEROXIDE ANION; HANTZSCH 1,4-DIHYDROPYRIDINES; OXIDATION; REDUCTION; OXYGEN; DIOXYGEN; KINETICS; ELECTRON; ANALOGS; COUPLE;

D O I：

10.3762/bjoc.11.234

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by O-3(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O-2. In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions.

引用

页码：2166 / 2170

页数：5

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