High-Temperature Water Gas Shift Reaction Over Fe/Al/Cu Oxide Based Catalysts Using Simulated Waste-Derived Synthesis Gas

被引：57

作者：

Jeong, Dae-Woon ^{[1
]}

Subramanian, Vijayanand ^{[1
]}

Shim, Jae-Oh ^{[1
]}

Jang, Won-Jun ^{[1
]}

Seo, Yong-Chil ^{[1
]}

Roh, Hyun-Seog ^{[1
]}

Gu, Jae Hoi ^{[2
]}

Lim, Yong Taek ^{[2
]}

机构：

[1] Yonsei Univ, Dept Environm Engn, Wonju 220710, Gangwon, South Korea

[2] Inst Adv Engn, Plant Engn Ctr, Suwon 443749, Gyeonggi, South Korea

来源：

CATALYSIS LETTERS | 2013年 / 143卷 / 05期

基金：

新加坡国家研究基金会;

关键词：

Waste-derived synthesis gas; Water gas shift (WGS); Fe/Al/Cu; Reducibility; Synergy effect; Stability; IRON-BASED CATALYSTS; SIZED PT/CEO2 CATALYST; FE-AL-CU; GASIFICATION TECHNOLOGIES; COPPER; PROMOTER; ENERGY;

D O I：

10.1007/s10562-013-0981-y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Simulated waste-derived synthesis gas has been tested for hydrogen production through water gas shift (WGS) reaction in the temperature range of 350-550 degrees C over chromium free Fe/Al/Cu oxide based catalysts. The CuO loading amount was optimized to get highly active Fe/Al/Cu oxide based catalysts for the high temperature WGS. Despite the high CO content in the feed gas (38.2 % dry basis), 15 % CuO catalyst exhibited the highest CO conversion (86 %) and 100 % selectivity to CO2 at a very high gas hourly space velocity (GHSV) of 40,057 h(-1) due to easier reducibility, the synergy effect of copper and aluminum, and the stability of the active phase (magnetite: Fe3O4).

引用

页码：438 / 444

页数：7

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