Hydrothermal synthesis and crystal structure of a novel layered vanadate with 1,4-diazabicyclo[2.2.2]octane as the structure-directing agent: (C6H14N2)V6O14 center dot H2O

被引：79
|
作者：
Nazar, LF
Koene, BE
Britten, JF
机构：
[1] Department of Chemistry, McMaster University, Hamilton, Ont.
[2] Department of Chemistry, University of Waterloo, Guelph-Waterloo Ctr. Grad. Wk. Chem., Waterloo
来源：
CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 02期
关键词：
D O I：
10.1021/cm9504302
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first hydrothermal synthesis and crystal structure of a novel organically templated layered vanadium oxide is described; the structural units of (C6H14N2)V6O14 are comprised of a unique arrangement of VO5 square pyramids and VO4 tetrahedra that are interconnected to form highly puckered sheets that are separated by diazabicyclooctane cations which act as the template in the synthesis.
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页码：327 / &
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