Hydrothermal synthesis and crystal structure of a novel layered vanadate with 1,4-diazabicyclo[2.2.2]octane as the structure-directing agent: (C6H14N2)V6O14 center dot H2O

被引：79
作者：
Nazar, LF
Koene, BE
Britten, JF
机构：
[1] Department of Chemistry, McMaster University, Hamilton, Ont.
[2] Department of Chemistry, University of Waterloo, Guelph-Waterloo Ctr. Grad. Wk. Chem., Waterloo
来源：
CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 02期
关键词：
D O I：
10.1021/cm9504302
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first hydrothermal synthesis and crystal structure of a novel organically templated layered vanadium oxide is described; the structural units of (C6H14N2)V6O14 are comprised of a unique arrangement of VO5 square pyramids and VO4 tetrahedra that are interconnected to form highly puckered sheets that are separated by diazabicyclooctane cations which act as the template in the synthesis.
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页码：327 / &
相关论文
共 31 条
[1]   VANADIUM PENTOXIDE XEROGEL AS RECHARGEABLE CATHODIC MATERIAL FOR LITHIUM BATTERIES [J].
BADDOUR, R ;
PEREIRARAMOS, JP ;
MESSINA, R ;
PERICHON, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 277 (1-2) :359-366
[2]   REFINING CRYSTAL-STRUCTURE OF ALPHA-VANADIUM SODIUM OXYBRONZE NAV2O5ALPHA [J].
CARPY, A ;
GALY, J .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (MAY15) :1481-1482
[3]   OXYFLUORINATED MICROPOROUS COMPOUNDS .11. SYNTHESIS AND CRYSTAL-STRUCTURE OF ULM-10 - THE 1ST BIDIMENSIONAL MIXED-VALENCE IRON FLUOROPHOSPHATE WITH INTERCALATED ETHYLENEDIAMINE [J].
CAVELLEC, M ;
RIOU, D ;
FEREY, G .
JOURNAL OF SOLID STATE CHEMISTRY, 1994, 112 (02) :441-442
[4]   ELECTROCHEMICAL AND STRUCTURAL CHARACTERIZATION OF LITHIUM INTERCALATION AND DEINTERCALATION IN THE GAMMA-LIV2O5 BRONZE [J].
COCCIANTELLI, JM ;
MENETRIER, M ;
DELMAS, C ;
DOUMERC, JP ;
POUCHARD, M ;
HAGENMULLER, P .
SOLID STATE IONICS, 1992, 50 (1-2) :99-105
[5]  
CROUCHBAKER S, 1988, P ELECTROCHEM SOC, V88, P44
[6]   NEW VISTAS IN ZEOLITE AND MOLECULAR-SIEVE CATALYSIS [J].
DAVIS, ME .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (03) :111-115
[7]   OMEGA-LIXV2O5 - A NEW ELECTRODE MATERIAL FOR RECHARGEABLE LITHIUM BATTERIES [J].
DELMAS, C ;
BRETHES, S ;
MENETRIER, M .
JOURNAL OF POWER SOURCES, 1991, 34 (02) :113-118
[8]   A REFINEMENT OF THE STRUCTURE OF V2O5 [J].
ENJALBERT, R ;
GALY, J .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1986, 42 :1467-1469
[9]   VANADIUM PENTOXIDE AND VANADIUM-OXIDE BRONZES STRUCTURAL CHEMISTRY OF SINGLE (S) AND DOUBLE (D) LAYER MXV2O5 PHASES [J].
GALY, J .
JOURNAL OF SOLID STATE CHEMISTRY, 1992, 100 (02) :229-245
[10]  
GALY J, 1971, REV CHIM MINER, V8, P509
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