Generation and reactivity of a 3H-phosphaindene:: the first 3H-phosphole

被引：13

作者：

Aitken, RA ^{[1
]}

Clasper, PN ^{[1
]}

Wilson, NJ ^{[1
]}

机构：

[1] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 28期

关键词：

phospholes; phosphaalkenes; phosphorus heterocycles; gas phase reactions;

D O I：

10.1016/S0040-4039(99)00999-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By gas-phase pyrolysis over a solid base the title compound has been prepared as a 1:1 mixture with its hydration product and characterised spectroscopically; the hindered C=P double bond is surprisingly unreactive. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：5271 / 5274

页数：4

共 14 条

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