Glycerol as a recyclable solvent in a microwave-assisted synthesis of disulfides

被引：27

作者：

Cabrera, Daiane M. L. ^{[1
]}

Libero, Francieli M. ^{[1
]}

Alves, Diego ^{[1
]}

Perin, Gelson ^{[1
]}

Lenardao, Eder J. ^{[1
]}

Jacob, Raquel G. ^{[1
]}

机构：

[1] Univ Fed Pelotas UFPel, CCQFA, LASOL, Pelotas, RS, Brazil

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2012年 / 5卷 / 03期

关键词：

glycerol; disulfides; green chemistry; microwave; OXIDATIVE TRANSFORMATION; SYMMETRICAL DISULFIDES; CATALYTIC-OXIDATION; ORGANIC-COMPOUNDS; THIOLS; EFFICIENT; CONVERSION; REAGENT; ACID; CECL3-CENTER-DOT-7H(2)O;

D O I：

10.1080/17518253.2011.631942

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present here a clean and fast synthesis of organic disulfides starting from thiols using glycerol as solvent under microwave irradiation. This efficient method is general for aromatic, aliphatic, and functionalized thiols, affording the corresponding disulfides in good to excellent yields after easy work up. Glycerol can be easily recovered and utilized for further oxidation reactions.

引用

页码：329 / 336

页数：8

共 72 条

[61] A novel method for the syntheses of symmetrical disulfides using CsF-Celite as a solid base [J].

Shah, STA ;

Khan, KM ;

Fecker, M ;

Voelter, W .

TETRAHEDRON LETTERS, 2003, 44 (35) :6789-6791

[62] Catalytic oxidation of thiols to disulfides using iodine and CeCl3•7H2O in graphite [J].

Silveira, Claudio C. ;

Mendes, Samuel R. .

TETRAHEDRON LETTERS, 2007, 48 (42) :7469-7471

[63] Glycerin and CeCl3•7H2O: a new and efficient recyclable medium for the synthesis of bis(indolyl)methanes [J].

Silveira, Claudio C. ;

Mendes, Samuel R. ;

Libero, Francieli M. ;

Lenardao, Eder J. ;

Perin, Gelson .

TETRAHEDRON LETTERS, 2009, 50 (44) :6060-6063

[64] Metal-Free Air Oxidation of Thiols in Recyclable Ionic Liquid: A Simple and Efficient Method for the Synthesis of Disulfides [J].

Singh, Devender ;

Galetto, Fabio Z. ;

Soares, Letiere C. ;

Rodrigues, Oscar E. Dorneles ;

Braga, Antonio Luiz .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (14) :2661-2665

[65]

Tajbakhsh M, 2007, J CHEM RES, P486

[66] Base-free oxidation of thiols to disulfides using selenium ionic liquid [J].

Thurow, Samuel ;

Pereira, Vanda A. ;

Martinez, Debora M. ;

Alves, Diego ;

Perin, Gelson ;

Jacob, Raquel G. ;

Lenardao, Eder J. .

TETRAHEDRON LETTERS, 2011, 52 (05) :640-643

[67]

Uemura S., 1991, COMPREHENSIVE ORGANI, P757

[68] KF/Al2O3 and PEG-400 as a recyclable medium for the selective α-selenation of aldehydes and ketones. Preparation of potential antimicrobial agents [J].

Victoria, Francine Novack ;

Radatz, Catia S. ;

Sachini, Maraisa ;

Jacob, Raquel G. ;

Perin, Gelson ;

da Silva, Wladimir P. ;

Lenardao, Eder J. .

TETRAHEDRON LETTERS, 2009, 50 (49) :6761-6763

[69] Green Route for Rapid Synthesis of 2,2'-Dithiobis(benzothiazole) by Microwave Irradiation [J].

Wang, Xin ;

Chen, Xianliang ;

Wu, Xiaojing ;

Tao, Jingqiu ;

Cheng, Ling .

SYNTHETIC COMMUNICATIONS, 2009, 39 (19) :3453-3458

[70] On the freshwater ecotoxicity and biodegradation properties of some common ionic liquids [J].

Wells, Andrew S. ;

Coombe, Vyvyan T. .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2006, 10 (04) :794-798

← 1 2 3 4 5 6 7 8 →