Glycerol as a recyclable solvent in a microwave-assisted synthesis of disulfides

被引:27
作者
Cabrera, Daiane M. L. [1 ]
Libero, Francieli M. [1 ]
Alves, Diego [1 ]
Perin, Gelson [1 ]
Lenardao, Eder J. [1 ]
Jacob, Raquel G. [1 ]
机构
[1] Univ Fed Pelotas UFPel, CCQFA, LASOL, Pelotas, RS, Brazil
关键词
glycerol; disulfides; green chemistry; microwave; OXIDATIVE TRANSFORMATION; SYMMETRICAL DISULFIDES; CATALYTIC-OXIDATION; ORGANIC-COMPOUNDS; THIOLS; EFFICIENT; CONVERSION; REAGENT; ACID; CECL3-CENTER-DOT-7H(2)O;
D O I
10.1080/17518253.2011.631942
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present here a clean and fast synthesis of organic disulfides starting from thiols using glycerol as solvent under microwave irradiation. This efficient method is general for aromatic, aliphatic, and functionalized thiols, affording the corresponding disulfides in good to excellent yields after easy work up. Glycerol can be easily recovered and utilized for further oxidation reactions.
引用
收藏
页码:329 / 336
页数:8
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