Glycerol as a recyclable solvent in a microwave-assisted synthesis of disulfides

被引：27

作者：

Cabrera, Daiane M. L. ^{[1
]}

Libero, Francieli M. ^{[1
]}

Alves, Diego ^{[1
]}

Perin, Gelson ^{[1
]}

Lenardao, Eder J. ^{[1
]}

Jacob, Raquel G. ^{[1
]}

机构：

[1] Univ Fed Pelotas UFPel, CCQFA, LASOL, Pelotas, RS, Brazil

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2012年 / 5卷 / 03期

关键词：

glycerol; disulfides; green chemistry; microwave; OXIDATIVE TRANSFORMATION; SYMMETRICAL DISULFIDES; CATALYTIC-OXIDATION; ORGANIC-COMPOUNDS; THIOLS; EFFICIENT; CONVERSION; REAGENT; ACID; CECL3-CENTER-DOT-7H(2)O;

D O I：

10.1080/17518253.2011.631942

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present here a clean and fast synthesis of organic disulfides starting from thiols using glycerol as solvent under microwave irradiation. This efficient method is general for aromatic, aliphatic, and functionalized thiols, affording the corresponding disulfides in good to excellent yields after easy work up. Glycerol can be easily recovered and utilized for further oxidation reactions.

引用

页码：329 / 336

页数：8

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