30-electron cationic iron- and cobalt-containing triple-decker complexes with a central cyclopentadienyl ligand.: The first synthesis of the parent triple-decker iron complex with cyclopentadienyl ligands, [(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)]PF6

被引：32

作者：

Kudinov, AR ^{[1
]}

Fil'chikov, AA ^{[1
]}

Petrovskii, PV ^{[1
]}

Rybinskaya, MI ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 07期

关键词：

sandwich compounds; triple-decker complexes; iron; cobalt; ferrocene;

D O I：

10.1007/BF02495303

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The parent 30-electron triple-decker iran complex with cyclopentadienyl ligands, [(eta-C5H5)Fe(mu-eta:eta-C5H5)Fe(eta-C5H5)]PF6 (1), was prepared for the first time by visible-light irradiation of ferrocene and [(eta-C5H5)Fe(eta-C6H6)]PF6 in CH2Cl2 at 0 degrees C. An analogous reaction performed with the use of (eta-C5H5)Co(eta-C4Me4) (2) instead of ferrocene afforded the thermally labile 30-electron cationic iron-cobalt triple-decker complex [(eta-C5H5)Fe(mu-eta:eta-C5H5)Co(eta-C4Me4)]PF6. The latter reacted with compound 2 at 20 degrees C to form the symmetrical 30-electron cationic dicobalt triple-decker complex [(eta-C4Me4)Co(mu-eta:eta-C5H5)Co(eta-C4Me4)]PF6.

引用

页码：1352 / 1355

页数：4

共 50 条

[31] Organometallic cluster complexes with face-capping arene ligands, 9.: Hydrogenation of the side-chain in [{(C5H5)Co}3(μ3-alkenylbenzene)]:: synthesis and structure of the cluster complexes [{(C5H5)Co}3(μ3-η22:η2:η2-C6H5-CHR1-CH2R2)]
Wadepohl, H
Büchner, K
Herrmann, M
Pritzkow, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 573 (1-2) : 22 - 29
[32] Synthesis and characterization of organoiron bifunctional complexes (C5H5)Fe(CO)(2)SCO(C6H4)COX (X=RS, RO, RCOO, R2N)
Jibril, I
Ali, AK
Omar, JT
[J]. POLYHEDRON, 1997, 16 (19) : 3327 - 3331
[33] COMPLEXATION CHEMISTRY OF PERHALOGENATED CYCLOPENTADIENES AND ALKYNES .16. PREPARATION OF PI-CYCLOPENTADIENYL COMPLEXES WITH 2 AND 3 CHALCOGEN SUBSTITUENTS ON A RING [C(5)CL(4-M)(ER)(M)(ER')ML(N) (ML(N)=MNCO3, FE(C5H5) M=1 OR 2, E=S, SE, R, R'=ME, PH) - STRUCTURE OF [C(5)CL(3)(SME)(2)][C5H5]FE
SUNKEL, K
BIRK, U
BLUM, A
KEMPINGER, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 465 (1-2) : 167 - 174
[34] Photochemical substitution of benzene in the iron cyclohexadienyl complex [(η5-C6H7)Fe(η-C6H6)]+
Loginov, D. A.
Vinogradov, M. M.
Starikova, Z. A.
Petrovskii, P. V.
Kudinov, A. R.
[J]. RUSSIAN CHEMICAL BULLETIN, 2007, 56 (11) : 2162 - 2165
[35] Photochemical substitution of benzene in the iron cyclohexadienyl complex [(η5-C6H7)Fe(η-C6H6)]+
D. A. Loginov
M. M. Vinogradov
Z. A. Starikova
P. V. Petrovskii
A. R. Kudinov
[J]. Russian Chemical Bulletin, 2007, 56 : 2162 - 2165
[36] Heterometallic nitrido-carbonyl clusters synthesis and characterization of [Fe5MN(CO)14(C5H5)]2- [Fe3M3N(CO)18]3- (M = Mo, W) and [HFe5MoN(CO)16]2- and solid-state structures of [Fe5MoN(CO)14(C5H5)]2-, [Fe5WN(CO)14(C5H5)]2-, and [Fe3Mo3N(CO)18]3-
Della Pergola, R
Branchini, M
Fumagalli, A
Garlaschelli, L
Manassero, M
Sansoni, M
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (08) : 1759 - 1765
[37] Photochemical replacement of benzene in the tetramethylcyclopentadienyl complex of iron, [η-C5Me4H)Fe(η-C6H6)]+
D. A. Loginov
I. D. Baravi
O. I. Artyushin
Z. A. Starikova
P. V. Petrovskii
A. R. Kudinov
[J]. Russian Chemical Bulletin, 2010, 59 : 1312 - 1316
[38] Photochemical replacement of benzene in the tetramethylcyclopentadienyl complex of iron, [(η-C5Me4H)Fe(η-C6H6)]+
Loginov, D. A.
Baravi, I. D.
Artyushin, O. I.
Starikova, Z. A.
Petrovskii, P. V.
Kudinov, A. R.
[J]. RUSSIAN CHEMICAL BULLETIN, 2010, 59 (07) : 1312 - 1316
[39] Synthesis and characterization of polyaromatic azine derivatives of (eta(5)-C5H5)Fe(CO)(2) and (eta(5)-C9H7)Fe(CO)(2): X-ray crystal structures of 4-[(eta(5)-cyclopentadienyl)irondicarbonyl]-7-chloroquinoline, 2-[(eta(5)-cyclopentadienyl)irondicarbonyl]-3-chloroquinoxaline, and 2-[(eta(5)-indenyl)irondicarbonyl]-3-chloroquinoxaline
Hunter, AD
Chukwu, R
Santarsiero, BD
Bott, SG
Atwood, JL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 526 (01) : 1 - 14
[40] Synthesis, alkylation, crystal structure and molecular mechanics investigations of the (methylthio)acetyliron complex [(eta(5)-C5H5)Fe(CO)(PPh(3))COCH2SCH3]
Wisniewski, K
Pakulski, Z
Zamojski, A
Sheldrick, WS
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 523 (01) : 1 - 7

← 1 2 3 4 5 →