30-electron cationic iron- and cobalt-containing triple-decker complexes with a central cyclopentadienyl ligand.: The first synthesis of the parent triple-decker iron complex with cyclopentadienyl ligands, [(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)]PF6

被引：32

作者：

Kudinov, AR ^{[1
]}

Fil'chikov, AA ^{[1
]}

Petrovskii, PV ^{[1
]}

Rybinskaya, MI ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 07期

关键词：

sandwich compounds; triple-decker complexes; iron; cobalt; ferrocene;

D O I：

10.1007/BF02495303

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The parent 30-electron triple-decker iran complex with cyclopentadienyl ligands, [(eta-C5H5)Fe(mu-eta:eta-C5H5)Fe(eta-C5H5)]PF6 (1), was prepared for the first time by visible-light irradiation of ferrocene and [(eta-C5H5)Fe(eta-C6H6)]PF6 in CH2Cl2 at 0 degrees C. An analogous reaction performed with the use of (eta-C5H5)Co(eta-C4Me4) (2) instead of ferrocene afforded the thermally labile 30-electron cationic iron-cobalt triple-decker complex [(eta-C5H5)Fe(mu-eta:eta-C5H5)Co(eta-C4Me4)]PF6. The latter reacted with compound 2 at 20 degrees C to form the symmetrical 30-electron cationic dicobalt triple-decker complex [(eta-C4Me4)Co(mu-eta:eta-C5H5)Co(eta-C4Me4)]PF6.

引用

页码：1352 / 1355

页数：4

共 50 条

[21] Mono- and bis(cyclopalladation) of the bis(ferrocenylimine) [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-CH=N-(C6H3-2-CH3)-}](2)
Lopez, C
Bosque, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 524 (1-2) : 247 - 252
[22] Design and synthesis of a redox-active Tc-99m radiopharmaceutical with ferrocenedithiocarboxylate [FcCS=Fe(C5H4CS2)(C5H5)-]
Uccelli, L
Bolzati, C
Boschi, A
Duatti, A
Morin, C
Pasqualini, R
Giganti, M
Piffanelli, A
NUCLEAR MEDICINE AND BIOLOGY, 1999, 26 (01) : 63 - 67
[23] A comparison of the rates of alkyl migration in the complexes [CpM(CO)(2)R](M=Fe,Ru,Os; Cp=eta(5)-C5H5)
George, R
Andersen, JAM
Moss, JR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 505 (01) : 131 - 133
[24] Hindering the formation of ferrocenes:: mono(cyclopentadienyl)halo iron complexes [Fe(C5R5)X] containing a sterically bulky cyclopentadienyl ligand
Okuda, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 786 - 792
[25] Symmetrization reaction of mercurated ferrocenylimines. X-ray crystal structure of [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NC6H4-4-Br)}(2)]
Liu, YH
Wu, YJ
Huo, SQ
Yuan, HZ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 534 (1-2) : 7 - 13
[26] Kinetics and mechanism of the photolytic CO-substitutions of cyclopentadienyl(dicarbonyl)iron thiocarboxylate complexes, Cp′Fe(CO)2SCOR (Cp′ = C5H5, ButC5H4,1,3-Bu2tC5H3; R = alkyl, aryl)
Khalid M. Tawarah
Ibrahim Jibril
Mutasem Z. Bani-Fwaz
Transition Metal Chemistry, 2000, 25 : 659 - 663
[27] Synthesis and crystal structure of N-ferrocenyl substituted heterocyclic imine ligands and their reactivity towards Fe-2(CO)(9); crystal structure of [mu(2)-eta(3)-(Fc)N-CH2-C=C-C(H)=C(H)-NMe]Fe-2(CO)(6) (Fc=(eta(5)-C5H5)Fe(eta(5)-C5H4))
Imhof, W
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 541 (1-2) : 109 - 116
[28] Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H6)]2+ (M = Rh, Ir)
Romanov, A. S.
Muratov, D. V.
Antipin, M. Yu.
Kudinov, A. R.
RUSSIAN CHEMICAL BULLETIN, 2009, 58 (05) : 971 - 973
[29] 1ST STRUCTURAL EVIDENCE FOR COMPLEXES CONTAINING ARSADIPHOSPHOLYL ANIONS - CRYSTAL-STRUCTURE OF THE IRON(II) COMPLEX [FE(ETA(5)-C5H5)(ETA(5)-C2(T)BU2ASP2)W(CO)5]
ALJUAID, SS
HITCHCOCK, PB
JOHNSON, JA
NIXON, JF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) : 45 - 50
[30] Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H6)]2+ (M = Rh, Ir)
A. S. Romanov
D. V. Muratov
M. Yu. Antipin
A. R. Kudinov
Russian Chemical Bulletin, 2009, 58 : 971 - 973

← 1 2 3 4 5 →