A Metal-Organic Framework as Attractive Cryogenic Magnetorefrigerant

被引：115

作者：

Sibille, Romain ^{[1
]}

Mazet, Thomas ^{[1
]}

Malaman, Bernard ^{[1
]}

Francois, Michel ^{[1
]}

机构：

[1] Univ Lorraine, Fac Sci, Inst Jean Lamour, Equipe 103,UMR7198, F-54506 Vandoeuvre Les Nancy, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 41期

关键词：

gadolinium; magnetic properties; magnetocaloric effect; metal-organic frameworks; molecular refrigerant; ADIABATIC DEMAGNETIZATION; MAGNETOCALORIC MATERIALS; REFRIGERATION; TEMPERATURES; ABSOLUTE;

D O I：

10.1002/chem.201200861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magnetocaloric effect: A Gd III-based metal-organic framework (MOF) has an unprecedented large magnetocaloric effect around 2 K. It was shown to be an interesting magnetorefrigerant for ultralow-temperature applications, because it combines the advantages of molecular materials and the robustness of a framework with strong 3D chemical connections (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12970 / 12973

页数：4

共 33 条

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