Emerging Organometallic Methods for the Synthesis of C-Branched (Hetero)aryl, Alkenyl, and Alkyl Glycosides: C-H Functionalization and Dual Photoredox Approaches

被引：65

作者：

Ghouilem, Juba ^{[1
]}

de Robichon, Morgane ^{[2
]}

Le Bideau, Franck ^{[1
]}

Ferry, Angelique ^{[2
]}

Messaoudi, Samir ^{[1
]}

机构：

[1] Univ Paris Saclay, Fac Pharm, CNRS, BioCIS, F-92290 Chatenay Malabry, France

[2] CY Cergy Paris Univ, BioCIS, CNRS, Equipe Chim Biol, F-95000 Neuville Sur Oise, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2021年 / 27卷 / 02期

关键词：

C-H functionalization; glycosylation; homogeneous catalysis; photochemistry; transition metals; CATALYZED SYNTHESIS; NATURAL-PRODUCTS; ARYL; GLYCOSYLATION; GLYCALS; ARYLATION; ACCESS; DERIVATIVES; ACTIVATION; VITEXIN;

D O I：

10.1002/chem.202003267

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition-metal-catalyzed C-H functionalization and photoredox nickel dual catalysis have emerged as innovative and powerful avenues for the synthesis of C-branched glycosides. These two concepts have been recently established and provide efficient and mild methods for accessing a series of valuable complex C-branched glycosides of great interest. Herein, recent developments in the synthesis of C-branched aryl/alkenyl/alkyl glycosides through these two approaches are highlighted.

引用

页码：491 / 511

页数：21

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