Simultaneous reduction and N-doping of graphene oxides by low-energy N2+ ion sputtering

被引：21

作者：

Zhang, Liang ^{[1
]}

Ye, Yifan ^{[1
]}

Cheng, Dingling ^{[1
]}

Zhang, Wenhua ^{[1
]}

Pan, Haibin ^{[1
]}

Zhu, Junfa ^{[1
]}

机构：

[1] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China

来源：

CARBON | 2013年 / 62卷

基金：

中国国家自然科学基金;

关键词：

NITROGEN-DOPED GRAPHENE; X-RAY-ABSORPTION; ELECTRONIC-STRUCTURE; GRAPHITE OXIDE; CARBON; MONOLAYER; SPECTRA; GROWTH;

D O I：

10.1016/j.carbon.2013.06.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An easy and catalyst-free method was used to obtain N-doped reduced graphene oxides (N-RGO) through low-energy N-2(+) ion sputtering of graphene oxides (GO). The simultaneous reduction and N-doping of GO during the sputtering were systematically investigated by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure and Raman spectroscopy. The N-doping and reduction levels, which are determined by the N/C and O/C atomic ratios from the quantitative XPS analysis, respectively, can be easily controlled by varying the N-2(+) ion sputtering time. In addition, three different N species, namely, nitrile-like N, graphitic N and pyridinic N, can be distinguished in N-RGO. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：365 / 373

页数：9

共 44 条

[1] Kinetic Study of the Graphite Oxide Reduction: Combined Structural and Gravimetric Experiments under Isothermal and Nonisothermal Conditions [J].

Barroso-Bujans, Fabienne ;

Alegria, Angel ;

Colmenero, Juan .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (49) :21645-21651

[2] Oxygen reduction reactions on pure and nitrogen-doped graphene: a first-principles modeling [J].

Boukhvalov, Danil W. ;

Son, Young-Woo .

NANOSCALE, 2012, 4 (02) :417-420

[3] The electronic properties of graphene [J].

Castro Neto, A. H. ;

Guinea, F. ;

Peres, N. M. R. ;

Novoselov, K. S. ;

Geim, A. K. .

REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162

[4] Interpretation of Raman spectra of disordered and amorphous carbon [J].

Ferrari, AC ;

Robertson, J .

PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107

[5] Formation, stabilities, and electronic properties of nitrogen defects in graphene [J].

Fujimoto, Yoshitaka ;

Saito, Susumu .

PHYSICAL REVIEW B, 2011, 84 (24)

[6] Probing the Thermal Deoxygenation of Graphene Oxide Using High-Resolution In Situ X-ray-Based Spectroscopies [J].

Ganguly, Abhijit ;

Sharma, Surbhi ;

Papakonstantinou, Pagona ;

Hamilton, Jeremy .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (34) :17009-17019

[7] The rise of graphene [J].

Geim, A. K. ;

Novoselov, K. S. .

NATURE MATERIALS, 2007, 6 (03) :183-191

[8] Doping graphene with metal contacts [J].

Giovannetti, G. ;

Khomyakov, P. A. ;

Brocks, G. ;

Karpan, V. M. ;

van den Brink, J. ;

Kelly, P. J. .

PHYSICAL REVIEW LETTERS, 2008, 101 (02)

[9] Electronic structure of carbon nitride thin films studied by X-ray spectroscopy techniques [J].

Hellgren, N ;

Guo, JH ;

Luo, Y ;

Såthe, C ;

Agui, A ;

Kashtanov, S ;

Nordgren, J ;

Ågren, H ;

Sundgren, JE .

THIN SOLID FILMS, 2005, 471 (1-2) :19-34

[10] PREPARATION OF GRAPHITIC OXIDE [J].

HUMMERS, WS ;

OFFEMAN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339

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