Increased optical nonlinearities of graphene nanohybrids covalently functionalized by axially-coordinated porphyrins

被引：118

作者：

Wang, Aijian ^{[1
]}

Long, Lingliang ^{[2
]}

Zhao, Wei ^{[1
]}

Song, Yinglin ^{[3
]}

Humphrey, Mark G. ^{[4
]}

Cifuentes, Marie P. ^{[4
]}

Wu, Xingzhi ^{[3
]}

Fu, Yongsheng ^{[1
]}

Zhang, Dongdong ^{[2
]}

Li, Xiufen ^{[2
]}

Zhang, Chi ^{[1
,2
,4
]}

机构：

[1] Nanjing Univ Sci & Technol, Mol Mat Res Ctr, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

[2] Jiangsu Univ, China Australia Joint Res Ctr Funct Mol Mat, Sci Res Acad, Zhenjiang 212013, Peoples R China

[3] Soochow Univ, Sch Phys Sci & Technol, Suzhou 215006, Peoples R China

[4] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

CARBON | 2013年 / 53卷

基金：

中国国家自然科学基金;

关键词：

WALLED CARBON NANOTUBES; REVERSE SATURABLE ABSORPTION; HETEROTHIOMETALLIC CLUSTERS; PHOSPHORUS(V) PORPHYRINS; PHTHALOCYANINE MOIETIES; LIMITING PROPERTIES; ELECTRON-TRANSFER; HYBRID MATERIAL; GRAPHITE OXIDE; EXCITED-STATE;

D O I：

10.1016/j.carbon.2012.11.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two graphene oxide (GO)-based nanohybrid materials possessing covalent linkages to axially-coordinated tetraphenylporphyrin (TPP), GO-TPP, were prepared and were characterized by Fourier transform infrared (FT-IR), Ultraviolet-visible (UV-Vis) absorption, steady state fluorescence, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), thermogravimetric analysis (TGA), elemental analysis and Raman spectroscopic techniques. The nonlinear optical properties and optical limiting performance of GO, GO-TPP nanohybrids and the free porphyrins dihydroxotin(IV) tetraphenylporphyrin (SnTPP) and the phosphorus-cored porphyrin (PTPP) were investigated using nanosecond and picosecond Z-scan measurements at 532 nm. At the identical mass concentration of 0.2 mg mL(-1), GO-TPP nanohybrids exhibited enhanced nonlinear optical properties and optical limiting performance, ascribed to a combination of nonlinear scattering and/or two-photon absorption with reverse saturable absorption, and the photo-induced electron or energy transfer from the electron-donor porphyrin moiety to the acceptor graphene. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：327 / 338

页数：12

共 66 条

[11] Synthesis and linear and nonlinear absorption properties of dendronised ruthenium(II) phthalocyanine and naphthalocyanine [J].

Dasari, Raghunath R. ;

Sartin, Matthew M. ;

Cozzuol, Matteo ;

Barlow, Stephen ;

Perry, Joseph W. ;

Marder, Seth R. .

CHEMICAL COMMUNICATIONS, 2011, 47 (15) :4547-4549

[12]

de la Torre G, 2003, NANOTECHNOLOGY, V14, P765, DOI 10.1088/0957-4484/14/7/312

[13] The chemistry of graphene oxide [J].

Dreyer, Daniel R. ;

Park, Sungjin ;

Bielawski, Christopher W. ;

Ruoff, Rodney S. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240

[14] Effect of Various Aminated Single-Walled Carbon Nanotubes on the Epoxy Cross-Linking Reactions [J].

Gonzalez-Dominguez, J. M. ;

Gonzalez, M. ;

Anson-Casaos, A. ;

Diez-Pascual, A. M. ;

Gomez, M. A. ;

Martinez, M. T. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (15) :7238-7248

[15] Covalently porphyrin-functionalized single-walled carbon nanotubes: a novel photoactive and optical limiting donor-acceptor nanohybrid [J].

Guo, Zhen ;

Du, Feng ;

Ren, Dongmei ;

Chen, Yongsheng ;

Zheng, Jianyu ;

Liu, Zhibo ;

Tian, Jianguo .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (29) :3021-3030

[16] Ultrafast nonlinear optical response of carbon nanotubes functionalized with water soluble porphyrin [J].

Gupta, Jyotsana ;

Vijayan, C. ;

Maurya, Sandeep Kumar ;

Goswami, D. .

OPTICS COMMUNICATIONS, 2012, 285 (07) :1920-1924

[17] Preparation and Optical Limiting Properties of Multiwalled Carbon Nanotubes with π-Conjugated Metal-Free Phthalocyanine Moieties [J].

He, Nan ;

Chen, Yu ;

Bai, Jinrui ;

Wang, Jun ;

Blau, Werner J. ;

Zhu, Jinhui .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (30) :13029-13035

[18] Coherent Nonlinear Optical Response of Graphene [J].

Hendry, E. ;

Hale, P. J. ;

Moger, J. ;

Savchenko, A. K. ;

Mikhailov, S. A. .

PHYSICAL REVIEW LETTERS, 2010, 105 (09)

[19] PREPARATION OF GRAPHITIC OXIDE [J].

HUMMERS, WS ;

OFFEMAN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339

[20] Evidence of graphitic AB stacking order of graphite oxides [J].

Jeong, Hae-Kyung ;

Lee, Yun Pyo ;

Lahaye, Rob J. W. E. ;

Park, Min-Ho ;

An, Kay Hyeok ;

Kim, Ick Jun ;

Yang, Cheol-Woong ;

Park, Chong Yun ;

Ruoff, Rodney S. ;

Lee, Young Hee .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (04) :1362-1366

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