Synthesis of isosorbide based polyurethanes: An isocyanate free method

被引：153

作者：

Besse, Vincent ^{[1
]}

Auvergne, Remi ^{[1
]}

Carlotti, Stephane ^{[3
]}

Boutevin, Gilles ^{[2
]}

Otazaghine, Belkacem ^{[4
]}

Caillol, Sylvain ^{[1
]}

Pascault, Jean-Pierre ^{[5
]}

Boutevin, Bernard ^{[1
]}

机构：

[1] Ecole Super Chim Montpellier, Inst Charles Gerhardt Montpellier, Equipe Ingn & Architectures Macromol, UMR 5253, F-34296 Montpellier 5, France

[2] Specif Polymers, F-34830 Clapiers, France

[3] Univ Bordeaux 1, Ecole Natl Super Chim Biol & Phys, CNRS, Lab Chim Polymeres Organ,UMR 5629, F-33607 Pessac, France

[4] Ctr Mat Grande Diffus, Ecole Mines Ales, F-30319 Ales, France

[5] Univ Lyon, INSA Lyon, IMP, UMR5223, F-69621 Villeurbanne, France

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2013年 / 73卷 / 03期

关键词：

Polyhydroxyurethane; Isosorbide; Renewable resources; Thermal stability; Carbonate; CYCLIC CARBONATES; POLYADDITION; TRANSESTERIFICATION; DIISOCYANATE; REACTIVITY; EFFICIENT; NETWORKS; DIAMINES; AMINES; DIOLS;

D O I：

10.1016/j.reactfunctpolym.2013.01.002

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis of isocyanate free polyurethanes is a major concern. This paper first reports the synthesis of new biobased isosorbide dicyclocarbonates from isosorbide. Then polyhydroxyurethanes (PHUs) were synthesized by a cyclocarbonate-amine step growth polyaddition with four commercial diamines (e.g. jeffamine D-400, 1,10 diaminodecane, diethylenetriamine and isophoronediamine). These unprecedented products, obtained with high yield, were characterized by H-1 NMR, FTIR, DSC, SEC and TGA analyses. PHUs exhibited glass transition temperatures from -8 degrees C to 59 degrees C, and degradation temperatures (Td 5%) between 234 degrees C and 255 degrees C. Last but not least, the compounds produced during the degradation of these PHUs were analyzed by ATG-IR technique and showed that carbon dioxide and secondary amines are released. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：588 / 594

页数：7