(C)-(2,4-di-tert-butyl-6-{[(2S)-3,3-dimethyl-1-oxido-2-butyl]iminomethyl} phenolato)ethanol-cis-dioxomolybdenum(VI) at 100 K

被引：1

作者：

Hartung, J

Greb, M

Svoboda, I

Fuess, H

机构：

[1] Tech Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[3] Tech Univ Darmstadt, D-64287 Darmstadt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806000146

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The central atom in the title complex, [Mo(C21H32NO2)O-2( C2H6O)], is offset from the equatorial plane of a tetragonally distorted octahedron. This plane is defined by three donor atoms from a tridentate Schiff base auxiliary (O2N) and one oxo ligand. A second oxo ligand and an O donor atom of an ethanol molecule are located in axial positions of the coordination polyhedron. The absolute configuration at Mo is C. There are two molecules in the asymmetric unit.

引用

页码：M275 / M277

页数：3

共 16 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].