Black cumin seed (BCS): a non conventional adsorbent for the removal of Cu (II) from aqueous solution

被引:14
作者
Ahmad, Rais [1 ]
Haseeb, Shaziya [1 ]
机构
[1] Aligarh Muslim Univ, Dept Appl Chem, Fac Engn & Technol, Environm Res Lab, Aligarh 202002, Uttar Pradesh, India
关键词
Black cumin seed; Adsorption; Cu2+; Freundlich; SEM; METAL-IONS; COPPER(II) IONS; INDUSTRY WASTE; HEAVY-METALS; ADSORPTION; BIOSORPTION; ZINC; EQUILIBRIUM; KINETICS; SORPTION;
D O I
10.1080/19443994.2014.968627
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The present study reports the use of Black Cumin Seed as a non-conventional adsorbent for the removal of Cu2+ from aqueous solution. The various operational parameters such as contact time, pH, concentration, surfactant, and ionic strength have been investigated. The adsorbent was characterized by Fourier transform infrared spectroscopy and SEM analysis. The optimum equilibrium time and pH was found to be 30min and 6, respectively. The adsorption data was best fitted by pseudo-second order kinetic whereas the adsorption isotherm was best described by Freundlich model. The process was found to be spontaneous and endothermic in nature. The activation energy was also determined and the process was found to be chemisorptions in nature. Ninety-five percent of the adsorbed Cu2+ ion could be desorbed by 0.1N HCl solution and the spent adsorbent can be reused up to five times.
引用
收藏
页码:2512 / 2521
页数:10
相关论文
共 53 条
[1]   Adsorption of Cu2+ from aqueous solution onto iron oxide coated eggshell powder: Evaluation of equilibrium, isotherms, kinetics, and regeneration capacity [J].
Ahmad, Rais ;
Kumar, Rajeev ;
Haseeb, Shaziya .
ARABIAN JOURNAL OF CHEMISTRY, 2012, 5 (03) :353-359
[2]   Characterization and adsorption properties of tetrabutylammonium montmorillonite (TBAM) clay:: Thermodynamic and kinetic calculations [J].
Akçay, M .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 296 (01) :16-21
[3]   Predictions of binary sorption isotherms for the sorption of heavy metals by pine bark using single isotherm data [J].
Al-Asheh, S ;
Banat, F ;
Al-Omari, R ;
Duvnjak, Z .
CHEMOSPHERE, 2000, 41 (05) :659-665
[4]   Removal of chromium (III) by using coal as adsorbent [J].
Anwar, Jamil ;
Shafique, Umer ;
Salman, Muhammad ;
Waheed-uz-Zaman ;
Anwar, Shafique ;
Anzano, Jesus M. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 171 (1-3) :797-801
[5]   Construction a hybrid biosorbent using Scenedesmus quadricauda and Ca-alginate for biosorption of Cu(II), Zn(II) and Ni(II): Kinetics and equilibrium studies [J].
Bayramoglu, Guelay ;
Arica, M. Yakup .
BIORESOURCE TECHNOLOGY, 2009, 100 (01) :186-193
[6]   Equilibrium and thermodynamic studies on biosorption of Pb(II) onto Candida albicans biomass [J].
Baysal, Zuebeyde ;
Cinar, Ercan ;
Bulut, Yasemin ;
Alkan, Hueseyin ;
Dogru, Mehmet .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 161 (01) :62-67
[7]   Adsorption of metal ions onto Moroccan stevensite: kinetic and isotherm studies [J].
Benhammou, A ;
Yaacoubi, A ;
Nibou, L ;
Tanouti, B .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 282 (02) :320-326
[8]   Use of a NICA-Donnan approach for analysis of proton binding to a lignocellulosic substrate extracted from wheat bran [J].
Bouanda, J ;
Dupont, L ;
Dumonceau, J ;
Aplincourt, M .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 373 (03) :174-182
[9]   Zinc removal from aqueous solution using an industrial by-product phosphogypsum [J].
Cesur, Hasan ;
Balkaya, Nilgun .
CHEMICAL ENGINEERING JOURNAL, 2007, 131 (1-3) :203-208
[10]   Nigella sativa L.:: Chemical composition and physicochemical characteristics of lipid fraction [J].
Cheikh-Rouhou, Salma ;
Besbes, Souhail ;
Hentati, Basma ;
Blecker, Christophe ;
Deroanne, Claude ;
Attia, Hamadi .
FOOD CHEMISTRY, 2007, 101 (02) :673-681