Analysis of monosaccharides and oligosaccharides in the pulp and paper industry by use of capillary zone electrophoresis: a review

被引:19
作者
Hiltunen, Salla [1 ]
Siren, Heli [1 ]
机构
[1] Lappeenranta Univ Technol, LUT Chem, Lappeenranta 53851, Finland
关键词
Capillary zone electrophoresis; Carbohydrates; Hydrolysis; Derivatization; INDIRECT UV DETECTION; ENZYMATIC-HYDROLYSIS; SEPARATION; ACID; WOOD; GALACTOGLUCOMANNAN; BORATE;
D O I
10.1007/s00216-013-7031-x
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Carbohydrate analysis is an important source of the information required for understanding and control of pulp and paper processes. The behavior of cellulose and hemicelluloses in the process, carbohydrate-lignin interactions, and the enzymatic treatment of fibers are examples of situations for which reliable, fast, qualitative, and quantitative methods are required. New uses of lignocellulosic material have further increased the need for carbohydrate analysis. This review collates and summarizes the most important findings and approaches in the analysis of wood-based carbohydrates by use of capillary zone electrophoresis and provides an analysis of the effect of different conditions on the separation, showing the advantages and limitations of the methods used. It provides guidelines for achieving higher quality and improved separation efficiency in carbohydrate analysis.
引用
收藏
页码:5773 / 5784
页数:12
相关论文
共 43 条
[1]  
Bajpai P, 2012, BIOTECHNOLOGY FOR PULP AND PAPER PROCESSING, P7, DOI 10.1007/978-1-4614-1409-4_2
[2]   Evaluation of acid methanolysis for analysis of wood hemicelluloses and pectins [J].
Bertaud, F ;
Sundberg, A ;
Holmbom, B .
CARBOHYDRATE POLYMERS, 2002, 48 (03) :319-324
[3]  
Bjerre AB, 1996, 855EN RIS
[4]   GAS CHROMATOGRAPHIC SUGAR ANALYSIS IN HYDROLYZATES OF WOOD CONSTITUENTS - QUANTITATIVE DETERMINATION OF MIXTURES OF ARABINOSE XYLOSE MANNOSE GALACTOSE AND GLUCOSE AS THEIR TRIMETHYLSILYL ETHER DERIVATIVES [J].
BROWER, HE ;
JEFFERY, JE ;
FOLSOM, MW .
ANALYTICAL CHEMISTRY, 1966, 38 (02) :362-&
[5]  
Brown PR, 1994, ADV CHROMATOGRAPHY
[6]   QUANTITATIVE-DETERMINATION OF WOOD-DERIVED SOLUBLE OLIGOSACCHARIDES BY HPLC [J].
BUCHERT, J ;
SIIKAAHO, M ;
BAILEY, M ;
PULS, J ;
VALKEAJARVI, A ;
PERE, J ;
VIIKARI, L .
BIOTECHNOLOGY TECHNIQUES, 1993, 7 (11) :785-790
[7]   DETERMINATION OF CARBOHYDRATES BY CAPILLARY ZONE ELECTROPHORESIS WITH AMPEROMETRIC DETECTION AT A COPPER MICROELECTRODE [J].
COLON, LA ;
DADOO, R ;
ZARE, RN .
ANALYTICAL CHEMISTRY, 1993, 65 (04) :476-481
[8]   Analysis of carbohydrates in wood and pulps employing enzymatic hydrolysis and subsequent capillary zone electrophoresis [J].
Dahlman, O ;
Jacobs, A ;
Liljenberg, A ;
Olsson, AI .
JOURNAL OF CHROMATOGRAPHY A, 2000, 891 (01) :157-174
[9]   From plant biomass to bio-based chemicals: Latest developments in xylan research [J].
Deutschmann, Rudolf ;
Dekker, Robert F. H. .
BIOTECHNOLOGY ADVANCES, 2012, 30 (06) :1627-1640
[10]   Analysis of galactoglucomannans from spruce wood by capillary electrophoresis [J].
Doliska, Ales ;
Strnad, Simona ;
Ribitsch, Volker ;
Kleinschek, Karin Stana ;
Willfor, Stefan ;
Saake, Bodo .
CELLULOSE, 2009, 16 (06) :1089-1097