Redox-Active Metallacarborane-Decorated Octasilsesquioxanes. Electrochemical and Thermal Properties

被引：36

作者：

Cabrera-Gonzalez, Justo ^{[1
]}

Sanchez-Arderiu, Victor ^{[1
]}

Vinas, Clara ^{[1
]}

Parella, Teodor ^{[2
]}

Teixidor, Francesc ^{[1
]}

Nunez, Rosario ^{[1
]}

机构：

[1] Inst Ciencia Mat Barcelona ICMAB CSIC, Campus Univ Autonoma Barcelona, Barcelona 08193, Spain

[2] Univ Autonoma Barcelona, Serv Ressonancia Magnet Nucl, E-08193 Barcelona, Spain

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 22期

关键词：

POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; DENDRIMERS; COBALTABISDICARBOLLIDE; FERROCENYL; ASSEMBLIES; STABILITY; MOLECULES; CHEMISTRY; CATALYSIS; POLYMERS;

D O I：

10.1021/acs.inorgchem.6b02394

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polyanionic and electroactive hybrids based on octasilsesquioxanes bearing metallacarborane units are developed. They show remarkable solubility in organic solvents and outstanding thermal stability. The metal-lacarboranes act as independent units simultaneously undergoing the reversible redox process.

引用

页码：11630 / 11634

页数：5

共 51 条

[1] Redox-Active Silica Nanoparticles. 9. Synthesis, Electrochemistry, and Diffusion Properties of Caged Octakis(N-ferrocenoyl-3-aminopropyl)silsesquioxane [J].

Abad, David Ruiz ;

Henig, Joerg ;

Mayer, Hermann A. ;

Reissig, Thomas ;

Speiser, Bernd .

ORGANOMETALLICS, 2014, 33 (18) :4777-4783

[2] Metallocenyl dendrimers and their applications in molecular electronics, sensing, and catalysis [J].

Astruc, Didier ;

Ornelas, Catia ;

Ruiz, Jaime .

ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (07) :841-856

[3] The Redox Functions of Metallodendrimers [J].

Astruc, Didier ;

Ruiz, Jaime .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2015, 25 (01) :2-11

[4] A Theta-Shaped Amphiphilic Cobaltabisdicarbollide Anion: Transition From Monolayer Vesicles to Micelles [J].

Bauduin, Pierre ;

Prevost, Sylvain ;

Farras, Pau ;

Teixidor, Francesc ;

Diat, Olivier ;

Zemb, Thomas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (23) :5298-5300

[5] Cubic Octasilsesquioxanes, Cyclotetrasiloxanes, and Disiloxanes Maximally Functionalized with Silicon-Bridged Interacting Triferrocenyl Units [J].

Bruna, Sonia ;

Nieto, Daniel ;

Ma Gonzalez-Vadillo, Ana ;

Perles, Josefina ;

Cuadrado, Isabel .

ORGANOMETALLICS, 2012, 31 (08) :3248-3258

[6] Lyotropic Lamellar Phase Formed from Monolayered θ-Shaped Carborane-Cage Amphiphiles [J].

Brusselle, Damien ;

Bauduin, Pierre ;

Girard, Luc ;

Zaulet, Adnana ;

Vinas, Clara ;

Teixidor, Francesc ;

Ly, Isabelle ;

Diat, Olivier .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (46) :12114-12118

[7] Inorganic dendrimers: recent advances for catalysis, nanomaterials, and nanomedicine [J].

Caminade, Anne-Marie .

CHEMICAL SOCIETY REVIEWS, 2016, 45 (19) :5174-5186

[8]

Ceroni P., 2010, ELECTROCHEMISTRY FUN

[9] The effect of a paramagnetic metal ion within a molecule: comparison of the structurally identical paramagnetic [3,3-Fe(1,2-C2B9H11)2]- with the diamagnetic [3,3-Co(1,2-C2B9H11)2]- sandwich complexes [J].

Cioran, Ana M. ;

Teixidor, Francesc ;

Vinas, Clara .

DALTON TRANSACTIONS, 2015, 44 (06) :2809-2818

[10] Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes [J].

Cordes, David B. ;

Lickiss, Paul D. ;

Rataboul, Franck .

CHEMICAL REVIEWS, 2010, 110 (04) :2081-2173

← 1 2 3 4 5 6 →