Controllable synthesis of hollow mesoporous silica nanoparticles templated by kinetic self-assembly using a gemini surfactant

被引:26
作者
Li, Min
Zhang, Chun [1 ]
Yang, Xiang-Liang
Xu, Hui-Bi
机构
[1] Huazhong Univ Sci & Technol, Coll Life Sci & Technol, Wuhan 430074, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
ROOM-TEMPERATURE SYNTHESIS; PORE-STRUCTURE; SPHERES; ALUMINOSILICATE; MORPHOLOGY; INTERFACES; NANOSHEETS; STABILITY; PARTICLES; EVOLUTION;
D O I
10.1039/c3ra22805c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A gemini surfactant was used as a kinetic self-assembly template to synthesize hollow mesoporous silica nanoparticles (HMSNs). In this method, only one surfactant, one silica source of TEOS and one solvent (water) were used. This easy and general method might be applicable for the production of HMSNs with controllable pore size for versatile applications in catalysis and drug delivery.
引用
收藏
页码:16304 / 16307
页数:4
相关论文
共 43 条
[1]   Highly monodisperse zirconia-coated silica spheres and zirconia/silica hollow spheres with remarkable textural properties [J].
Arnal, Pablo M. ;
Weidenthaler, Claudia ;
Schueth, Ferdi .
CHEMISTRY OF MATERIALS, 2006, 18 (11) :2733-2739
[2]   A versatile method for the production of monodisperse spherical particles and hollow particles:: Templating from binary core-shell structures [J].
Arnal, PM ;
Schüth, F ;
Kleitz, F .
CHEMICAL COMMUNICATIONS, 2006, (11) :1203-1205
[3]   Aqueous-phase room-temperature synthesis of gold nanoribbons: Soft template effect of a gemini surfactant [J].
Bakshi, Mandeep Singh ;
Possmayer, Fred ;
Petersen, Nils O. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (22) :8259-8265
[4]   Hollow silica spheres with an ordered pore structure and their application in controlled release studies [J].
Botterhuis, NE ;
Sun, QY ;
Magusin, PCMM ;
van Santen, RA ;
Sommerdijk, NAJM .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (05) :1448-1456
[5]   Facile and Scalable Synthesis of Tailored Silica "Nanorattle" Structures [J].
Chen, Dong ;
Li, Linlin ;
Tang, Fangqiong ;
Qi, Shuo .
ADVANCED MATERIALS, 2009, 21 (37) :3804-3807
[6]   Synthesis of silica mesoporous crystals with controlled structure and morphology using gemini surfactant [J].
Chen, Qianru ;
Sakamoto, Yasuhiro ;
Terasaki, Osamu ;
Che, Shunai .
MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 105 (1-2) :24-33
[7]   Synthesis of monodispersed mesoporous silica spheres (MMSSs) with controlled particle size using gemini surfactant [J].
Chen, Qianru ;
Han, Lu ;
Gao, Chuanbo ;
Che, Shunai .
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 128 (1-3) :203-212
[8]   Reversible Pore-Structure Evolution in Hollow Silica Nanocapsules: Large Pores for siRNA Delivery and Nanoparticle Collecting [J].
Chen, Yu ;
Chu, Chen ;
Zhou, Yuchuan ;
Ru, Yanfei ;
Chen, Hangrong ;
Chen, Feng ;
He, Qianjun ;
Zhang, Yonglian ;
Zhang, Linlin ;
Shi, Jianlin .
SMALL, 2011, 7 (20) :2935-2944
[9]   Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts [J].
Choi, Minkee ;
Na, Kyungsu ;
Kim, Jeongnam ;
Sakamoto, Yasuhiro ;
Terasaki, Osamu ;
Ryoo, Ryong .
NATURE, 2009, 461 (7261) :246-U120
[10]   COOPERATIVE ORGANIZATION OF INORGANIC-SURFACTANT AND BIOMIMETIC ASSEMBLIES [J].
FIROUZI, A ;
KUMAR, D ;
BULL, LM ;
BESIER, T ;
SIEGER, P ;
HUO, Q ;
WALKER, SA ;
ZASADZINSKI, JA ;
GLINKA, C ;
NICOL, J ;
MARGOLESE, D ;
STUCKY, GD ;
CHMELKA, BF .
SCIENCE, 1995, 267 (5201) :1138-1143