Synthesis, structure, and reactivities of the η1:η6-μ2-aryl alkynyl diruthenium complex.: X-ray structure of [Cp(PPh3)2Ru(η1:η6-μ2-CCC6H4Me-p)RuCp*]PF6 (Cp = η5-C5H5, Cp* = η5-C5Me5)

被引:3
|
作者
Matsuzaka, H [1 ]
Sato, Y
Okimura, H
Ishii, T
Yamashita, M
Kitagawa, S
Kondo, M
Shiro, M
Yamasaki, M
机构
[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan
[2] Rigaku Corp, Xray Res Lab, Akishima, Tokyo 1968686, Japan
关键词
D O I
10.1246/cl.1999.865
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Preparation of a eta(1):eta(6)-mu(2)-aryl alkynyl diruthenium complex [Cp(PPh3)(2)Ru(eta(1):eta(6)-mu(2)-C=CC6H4Me-p)RuCp*]Cl (2 . Cl) [Cp = eta(5)-C5H5, Cp* = eta(5)-C5Me5] and its reactions with electrophile or CO are reported. The structure of 2 . PF6 has been determined by X-ray crystallography.
引用
收藏
页码:865 / 866
页数:2
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