Intermolecular hydroarylation of unactivated olefins catalyzed by homogeneous platinum complexes

被引：83
作者：
Luedtke, Avery T. [1 ]
Goldberg, Karen I. [1 ]
机构：
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 40期
基金：
美国国家科学基金会;
关键词：
arenes; C-H activation; hydroarylation; olefins; platinum;
D O I：
10.1002/anie.200800524
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Designing catalysts: The five-coordinate platinum(IV) complex A and the platinum(II) trans complex B act as precatalysts for the hydroarylation of unactivated olefins. The catalytic cycle features an aryl-olefin insertion at PtII and a C-H bond activation of the arene solvent as key steps. The Pt II cis complex C has been observed in hydroarylation reactions of ethylene with benzene. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7694 / 7696
页数：3
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