Organocatalytic Oxidative Dimerization of Alcohols to Esters

被引：29

作者：

Abramovich, Adi ^{[1
]}

Toledo, Hila ^{[1
]}

Pisarevsky, Evgeni ^{[1
]}

Szpilman, Alex M. ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel

来源：

SYNLETT | 2012年 / 15期

基金：

以色列科学基金会;

关键词：

catalysis; dimerization; alcohols; esters; oxidation; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; OXOAMMONIUM SALTS; BENZYLIC ALCOHOLS; CARBOXYLIC-ACIDS; DIMERIC ESTERS; ALDEHYDES; COMPLEXES; RUTHENIUM; ESTERIFICATION;

D O I：

10.1055/s-0032-1317018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2 mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.

引用

页码：2261 / 2265

页数：5

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