Wet versus slurry carbonation of EAF steel slag

被引:32
作者
Baciocchi, R.
Costa, G. [1 ]
Di Bartolomeo, E. [2 ]
Polettini, A. [3 ]
Pomi, R. [3 ]
机构
[1] Univ Roma Tor Vergata, Dept Civil Engn, Rome, Italy
[2] Univ Roma Tor Vergata, Dept Chem Sci & Technol, Rome, Italy
[3] Univ Roma La Sapienza, Dept Civil & Environm Engn, I-00184 Rome, Italy
关键词
carbonation; CO2; uptake; EAF steel slag; leaching; mineralogy; CO2; SEQUESTRATION; ACCELERATED CARBONATION; DIOXIDE;
D O I
10.1002/ghg.38
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The CO2 uptake and Ca-to-carbonate conversion yield attained by wet and slurry-phase carbonation of stainless steel slag are reported. A maximum CO2 uptake of 180 g CO2/kg slag was achieved under wet conditions (50 degrees C, 3 bar CO2, 0.4 l/kg), corresponding to a Ca-to-carbonate conversion yield of 50%. The slurry-phase process, even when adopting more energy-intensive operating conditions, did not improve the CO2 uptake kinetics and conversion yield in comparison to the wet treatment. The mineralogy of the carbonated slag exhibited a decreased content of silicate phases (Ca2SiO4 in particular), a marked reduction of Ca and Mg oxides, and a noteworthy increase of calcite. (C) 2011 Society of Chemical Industry and John Wiley & Sons, Ltd
引用
收藏
页码:312 / 319
页数:8
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