Compositional analysis of Hyperion with the Cassini Visual and Infrared Mapping Spectrometer

Compositional mapping of the surface of Hyperion using Cassini Visual and Infrared Mapping Spectrometer (VIMS) observations reveals a heterogeneous surface dominated by water ice accompanied by additional materials. Carbon dioxide, as evidenced by a prominent absorption band centered at 4.26 mu m, is distributed over most of the surface, including icy regions. This does not represent exposures of pure CO2 ice, but concentrations of CO2 molecules adsorbed on other materials or complexed in H2O, perhaps as a clathrate (Cruikshank, D.P., Meyer, A.W., Brown, R.H., Clark, R.N., Jaumann, R., Stephan, K., Hibbitts, CA., Sandford, S.A., Mastrapa, R., Filacchione, G., Dalle Ore, CM., Nicholson, P.D., Buratti, B.J., McCord, T.B., Nelson, R.M., Dalton, J.B., Baines, K.H., Matson, D.L., The VIMS Team [2010]. Icarus 206, 561-572). Localized deposits of low-albedo material in subcircular depressions exhibit spectral absorptions indicative of C-H in aromatic (3.29 mu m) and aliphatic (3.35-3.50 mu m) hydrocarbons. An absorption band at 2.42 mu m that is also seen on other saturnian satellites, tentatively identified as H-2 (Clark, R.N. et al. [2011]. In: Proc. AAS-DPS Meeting, 43, 1563; Clark et al., in preparation, 2012) adsorbed on dark material grains, is also prominent. Our best spectral models included H2O and CO2 ice, with small amounts of nanophase Fe and Fe2O3. Weaker and more spatially scattered absorption features are also found at 4.48, 4.60, and 4.89 mu m, although no clear molecular identifications have yet been made. While strongest in the low-albedo deposits, the CO2, hydrocarbon and putative H-2 bands vary in strength throughout the icy regions, as do the 4.48-, 4.60- and 4.89-mu m bands, suggesting that this background ice is laced with a complex mixture of non-ice compounds. (C) 2012 Elsevier Inc. All rights reserved.