Efficient preparation and improved sensitivity of molecularly imprinted polymers using room temperature ionic liquids

被引:66
作者
Booker, K
Bowyer, MC
Holdsworth, CI
McCluskey, A
机构
[1] Sch Environm & Life Sci, Callaghan, NSW 2308, Australia
[2] Univ Newcastle, Discipline Appl Sci, Ourimbah, NSW 2258, Australia
关键词
D O I
10.1039/b517886j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis of trans-aconitic acid molecularly imprinted polymers in [ bmim][BF4] and [bmim][PF6] under photochemical (5 degrees C, AIBN) and thermal ( 60 degrees C, AIBN) conditions gave polymer micro-spheres (<200 nm), under bulk and precipitation polymerisation conditions, and higher selectivity indices (100% improvement) relative to the more traditional precipitation polymerisation (CH3CN, high solvent volumes) approach.
引用
收藏
页码:1730 / 1732
页数:3
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