Efficient preparation and improved sensitivity of molecularly imprinted polymers using room temperature ionic liquids

被引：69

作者：

Booker, K

Bowyer, MC

Holdsworth, CI

McCluskey, A

机构：

[1] Sch Environm & Life Sci, Callaghan, NSW 2308, Australia

[2] Univ Newcastle, Discipline Appl Sci, Ourimbah, NSW 2258, Australia

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 16期

关键词：

D O I：

10.1039/b517886j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of trans-aconitic acid molecularly imprinted polymers in [ bmim][BF4] and [bmim][PF6] under photochemical (5 degrees C, AIBN) and thermal ( 60 degrees C, AIBN) conditions gave polymer micro-spheres (<200 nm), under bulk and precipitation polymerisation conditions, and higher selectivity indices (100% improvement) relative to the more traditional precipitation polymerisation (CH3CN, high solvent volumes) approach.

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收藏

页码：1730 / 1732

页数：3

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