Efficient preparation and improved sensitivity of molecularly imprinted polymers using room temperature ionic liquids

被引：67
|
作者：
Booker, K
Bowyer, MC
Holdsworth, CI
McCluskey, A
机构：
[1] Sch Environm & Life Sci, Callaghan, NSW 2308, Australia
[2] Univ Newcastle, Discipline Appl Sci, Ourimbah, NSW 2258, Australia
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 16期
关键词：
D O I：
10.1039/b517886j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthesis of trans-aconitic acid molecularly imprinted polymers in [ bmim][BF4] and [bmim][PF6] under photochemical (5 degrees C, AIBN) and thermal ( 60 degrees C, AIBN) conditions gave polymer micro-spheres (<200 nm), under bulk and precipitation polymerisation conditions, and higher selectivity indices (100% improvement) relative to the more traditional precipitation polymerisation (CH3CN, high solvent volumes) approach.
引用
收藏
页码：1730 / 1732
页数：3
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