Diallylaminoarenes: a new class of versatile ligands for silver(I) that consistently lead to one-dimensional polymeric metallosupramolecular assemblies

被引:7
作者
Kelemu, Solomon W. [1 ]
Steel, Peter J. [1 ]
机构
[1] Univ Canterbury, Dept Chem, Christchurch 8140, New Zealand
关键词
CRYSTAL-STRUCTURES; COORDINATION; COMPLEXES; FRAMEWORKS; ARCHITECTURES; DISCRETE; DESIGN; ION;
D O I
10.1039/c3ce41707g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ligands comprised of a diallylamino group attached to a phenyl, 2-pyridyl, 2-pyrimidyl, 2-thiazolyl and 2-quinolyl ring react with silver(I) salts (perchlorate and/or triflate) to faithfully assemble into 1-D coordination polymers, regardless of variation in the number of additional nitrogen donors, the counterion and the coordination number (three to five) of the silver atoms.
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页码:9064 / 9071
页数:8
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