Cobalt-Catalyzed Acceptorless Alcohol Dehydrogenation: Synthesis of Imines from Alcohols and Amines

被引：240

作者：

Zhang, Guoqi ^{[1
]}

Hanson, Susan K. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 03期

关键词：

OXIDANT-FREE OXIDATION; HOMOGENEOUS RUTHENIUM; HYDROGEN-PRODUCTION; BORROWING HYDROGEN; COMPLEXES; LIGAND; LIBERATION; GENERATION; CONVERSION; AMINATION;

D O I：

10.1021/ol303479f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cobalt catalyst has been developed for the acceptorless dehydrogenation of alcohols and applied to synthesize Imines from alcohols and amines. Deuterium labeling studies suggest that the reaction proceeds by an initial reversible alcohol dehydrogenation step involving a cobalt hydride intermediate.

引用

页码：650 / 653

页数：4

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