Particulate multilayers prepared from surfactant-stabilized SnO2 nanoparticles

被引:27
作者
Cao, LX
Huo, LH
Ping, GC
Wang, DM
Zeng, GF
Xi, SQ [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
[2] Southeast Univ, Natl Lab Mol & Biomol Elect, Nanjing 210096, Peoples R China
基金
中国国家自然科学基金;
关键词
SnO2; nanoparticles; Langmuir-Blodgett films; multilayers;
D O I
10.1016/S0040-6090(99)00002-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Surfactant-stabilized SnO2 nanoparticulate organosol was prepared. The organosol mixed with arachidic acid was spread on water surfaces in a Langmuir-Blodgett (LB) balance. Surface pressure versus surface area isotherms were determined. The surfactant-stabilized SnO2 nanoparticulate monolayers were transferred, layer-by-layer by the LB technique, to solid substrates. Then the multilayers were characterized by Fourier transform IR spectroscopy, UV-visible spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. The results indicate that the multilayer is composed of SnO2 nanoparticles and arachidic acid. It forms a Z-type periodic structure with a long spacing of 7.48 nm, i.e. a kind of three-dimensional superlattice. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:258 / 262
页数:5
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