The synthesis of cyclotriveratrylene using heteropolyacids (H3+xPMo12-xVxO40) as recyclable heterogeneous catalysts

被引：0
作者：
Gharib, A. [1 ,2 ]
Pesyan, N. N. [3 ]
Jahangir, M. [1 ]
Roshani, M. [1 ]
Scheeren, J. W. [4 ]
机构：
[1] Islamic Azad Univ, Dept Chem, Mashhad, Iran
[2] Agr Res & Serv Ctr, Mashhad, Iran
[3] Urmia Univ, Fac Sci, Dept Chem, Orumiyeh 57159, Iran
[4] Radboud Univ Nijmegen, Dept Organ Chem, NL-6525 ED Nijmegen, Netherlands
来源：
BULGARIAN CHEMICAL COMMUNICATIONS | 2012年 / 44卷 / 02期
关键词：
cyclotriveratrylene (CV); formaldehyde; heteropolyacid; catalyst; KEGGIN; SUBSTITUTION; EFFICIENT; ALCOHOLS; CRYSTAL; ACID;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of cyclotriveratrylene (CV) using formaldehyde (37%) in the presence of heteropolyacids, H3+xPMo12-xVxO40 (x = 1-3) was studied in different solvents. In all cases the heteropolyacid with x = 3 gave the highest yield using ethanol as solvent. The effects of the catalyst and the solvent on the reaction were studied.
引用
收藏
页码：118 / 121
页数：4
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