4-Chloro-2-(4-oxopent-2-en-2-ylamino)-phenol

被引:19
作者
Arici, C [1 ]
Tahir, MN
Ülkü, D
Atakol, O
机构
[1] Hacettepe Univ, Dept Engn Phys, TR-06532 Ankara, Turkey
[2] Ankara Univ, Dept Chem, TR-06100 Ankara, Turkey
关键词
D O I
10.1107/S0108270199008501
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, C11H12ClNO2, there is an intramolecular hydrogen bond between the amino group and the carbonyl O atom [N ... O 2.686(3)Angstrom]. Additional intermolecular hydrogen bonds between the phenol O atom and the carbonyl groups of neighbouring molecules [O ... O 2.634(2)Angstrom] form a polymeric chain. The molecule is not planar. The dihedral angle between the aromatic ring and the bidentate Schiff base moiety is 44.51(7)degrees. The characteristic Schiff base N-C bond length is 1.339(3)Angstrom.
引用
收藏
页码:1691 / 1692
页数:2
相关论文
共 7 条
[1]  
*ENRAFNONIUS, 1993, CAD 4 EXPRESS VERSIO
[2]  
FAIR CK, 1990, MOLEN INTERACTIVE IN
[3]   THE METHOD OF REPRESENTATIONS OF STRUCTURE SEMINVARIANTS .2. NEW THEORETICAL AND PRACTICAL ASPECTS [J].
GIACOVAZZO, C .
ACTA CRYSTALLOGRAPHICA SECTION A, 1980, 36 (MAY) :362-372
[4]   A reinvestigation of the quinoidal effect in N-n-propyl-2-oxo-1-naphthylidenemethylamine [J].
Kaitner, B ;
Pavlovic, G .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :2573-2575
[5]   5-chloro-2-[(2-hydroxybenzylidene)aminomethyl]phenol [J].
Kevran, S ;
Elmali, A ;
Elerman, Y .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :3256-3258
[6]  
SPEK AL, 1909, PLATON99 MOL GEOMETR
[7]   Bis[4-(5-chloro-2-hydroxyphenylimino-N,O:O)-2-penten-2-olato(2)-O]dicopper(II) [J].
Tahir, MN ;
Ulku, D ;
Atakol, O ;
Akay, A .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :2676-2678