Reactivity of [PtCl(η2-C2H4)(N-N)]+, N-N = diimine ligand, with phenol derivatives and first comparison between single crystal X-ray structures of syn- and anti-[Pt(N-N)(phenolate)2] rotamers in the solid state

被引：20

作者：

Benedetti, Michele ^{[1
]}

Antonucci, Daniela ^{[1
]}

Girelli, Chiara R. ^{[1
]}

Capitelli, Francesco ^{[2
]}

Fanizzi, Francesco P. ^{[1
]}

机构：

[1] Univ Salento, Dipartimento Sci & Tecnol Biol & Ambientali, Via Monteroni, I-73100 Lecce, Italy

[2] Inst Crystallog IC CNR, I-00016 Monterotondo, Italy

来源：

INORGANICA CHIMICA ACTA | 2014年 / 409卷

关键词：

Coordination chemistry; Platinum complexes; Dinitrogen ligands; Antitumor drugs; Rotamers; Single crystal X-ray structure; N7-PLATINATED GUANINES; CHIRAL DISCRIMINATION; CIRCULAR-DICHROISM; COMPLEXES; PLATINUM(II); DNA; NUCLEOPHILES; CHEMISTRY; ANALOGS; OXYGEN;

D O I：

10.1016/j.ica.2013.09.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work it is described a new synthetic pathway for the synthesis of bis-cresolate Pt(II) complexes with (N-N) dinitrogen ligands. In particular, we were able, for the first time, to isolate, in the solid state, both anti-[Pt(N-N)(OC6H4-4-Me)(2)], N-N = 1,10-phenanthroline, (head to tail) and syn-[Pt(N-N)(OC6H4-4-Me) (2)], N-N = 2,2'-bipyridyl, (head to head) rotamers, which were characterized as different rotamers in the solid state by single crystal X-ray diffraction. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：427 / 432

页数：6

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