Luminescent groups 10 and 11 heteropolynuclear complexes based on thiolate or alkynyl ligands

被引：149

作者：

Chen, Zhong-Ning ^{[1
]}

Zhao, Na ^{[1
]}

Fan, Yang ^{[1
]}

Ni, Jun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 1-2期

关键词：

Alkynyk; Coinage metal; Heteropolynuclear; Luminescence; Phosphine; Platinum; Thiolate; M-I M; MIXED-METAL PLATINUM(II)-COPPER(I); STRUCTURAL-CHARACTERIZATION; PLATINUM COMPLEXES; CRYSTAL-STRUCTURE; COORDINATION CHEMISTRY; MOLECULAR-STRUCTURES; ACETYLIDE COMPLEXES; EXCITED-STATE; AG;

D O I：

10.1016/j.ccr.2007.11.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of groups 10 and 11 heteropolynuclear thiolate or alkynyl complexes has been prepared by incorporating d(8) or d(10) metal thiolate/alkynyl species with d(10) metal diphosphine components. This review article presents our recent progress in the design of luminescent d(8) - d(10) or d(10) - d(10) multicomponent and heteropolynuclear complexes based on thiolate or alkynyl ligands. The syntheses, structures and photophysical properties of these heteropolynuclear thiolate/alkynyl complexes are summarized to elucidate the correlation between structures and luminescence. (C) 2007 Elsevier B.V All rights reserved.

引用

页码：1 / 20

页数：20

共 84 条

[1] Perspectives in syntheses, structures and bonding of acetylide-containing clusters of group 11 metals [J].

Abu-Salah, OM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 565 (1-2) :211-216

[2] Redox control of light-induced platinum-cluster-to-iron charge transfer in a bis(ferrocenylethynyl)-substituted hexanuclear platinum derivative [J].

Albinati, A ;

de Biani, FF ;

Leoni, P ;

Marchetti, L ;

Pasquali, M ;

Rizzato, S ;

Zanello, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) :5701-5705

[3] Versatile behavior of [Pt2Ag4(CC-t-Bu)8]:: Synthesis, structures, and properties of [{Pt2Ag4(CC-t-BU)8}{Ag(bipy)}]4+ and an unprecedented chain polymeric cocrystallization adduct with a 2,2′-bipy ligand [J].

Ara, I ;

Forniés, J ;

Gómez, J ;

Lalinde, E ;

Moreno, MT .

ORGANOMETALLICS, 2000, 19 (16) :3137-3144

[4] Synthesis, structures and photophysics of novel luminescent platinum-copper complexes [J].

Ara, I ;

Berenguer, JR ;

Eguizábal, E ;

Forniés, J ;

Gómez, J ;

Lalinde, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 670 (1-2) :221-234

[5]

ARA I, 1995, J CHEM SOC DA, V2397

[6] SYNTHESIS AND CHEMICAL BEHAVIOR OF PERCHLOROPHENYLACETYLENE [J].

BALLESTER, M ;

CASTANER, J ;

RIERA, J ;

TABERNERO, I .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (09) :1413-1419

[7] Novel luminescent mixed-metal Pt-Tl-alkynyl-based complexes:: The role of the alkynyl substituent in metallophilic and η2(π•••Tl)-bonding interactions [J].

Berenguer, JR ;

Forniés, J ;

Gil, B ;

Lalinde, E .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (03) :785-795

[8] Some molecular rods:: gold(I) complexes of 1,3-diynes.: Crystal structures of Au(C≡CC≡CH)(PPh3) and {Cu3(μ-dppm)3}(μ3-I)(μ3-C≡CC≡CAuC≡CC≡CH) [J].

Bruce, MI ;

Hall, BC ;

Skelton, BW ;

Smith, ME ;

White, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06) :995-1001

[9] Synthesis and reactivity of the first (hydrosulfido)gold(III) complex.: Crystal structure of the derivatives NBu4[{Au(C6F5)3}2SR] with the isolobal fragments R = H, AuPPh3, AgPPh3 [J].

Canales, F ;

Canales, S ;

Crespo, O ;

Gimeno, MC ;

Jones, PG ;

Laguna, A .

ORGANOMETALLICS, 1998, 17 (08) :1617-1621

[10] Unprecedented Pt-Pt bonded trimer {[Pt2Cu4(CCPh)8]}3 showing unusual near-infrared luminescence [J].

Charmant, JPH ;

Forniés, J ;

Gómez, J ;

Lalinde, E ;

Merino, RI ;

Moreno, MT ;

Orpen, AC .

ORGANOMETALLICS, 1999, 18 (17) :3353-3358

← 1 2 3 4 5 6 7 8 9 →