Selective catalytic transfer hydrogenation of nitriles to primary amines using Pd/C

被引：84

作者：

Vilches-Herrera, Marcelo ^{[1
]}

Werkmeister, Svenja ^{[1
]}

Junge, Kathrin ^{[1
]}

Boerner, Armin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Catalysis eV, D-18055 Rostock, Germany

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 03期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; BIOMIMETIC TRANSFER HYDROGENATION; LIQUID-PHASE; PRACTICAL SYNTHESIS; RANEY-NICKEL; REDUCTION; BENZONITRILE; FORMYLATION; KETONES; NITRO;

D O I：

10.1039/c3cy00854a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic transfer hydrogenation of (hetero)aryl nitriles using ammonium formate has been investigated in detail. In the presence of commercially available Pd/C, a straightforward and selective reduction is achieved without any additives under mild conditions.

引用

页码：629 / 632

页数：4

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