Ethanol-to-butadiene: the reaction and its catalysts

被引:119
作者
Pomalaza, Guillaume [1 ]
Ponton, Paola Arango [1 ]
Capron, Mickael [1 ]
Dumeignil, Franck [1 ]
机构
[1] Univ Lille, CNRS, UCCS Unite Catalyse & Chim Solide, Cent Lille,Univ Artois,UMR 8181, F-59000 Lille, France
关键词
LEWIS-ACID SITES; MEERWEIN-PONNDORF-VERLEY; PHASE ALDOL CONDENSATION; SUPPORTED TANTALUM OXIDE; BASE PROPERTIES; BIO-ETHANOL; MGO-SIO2; CATALYSTS; ONE-STEP; SN-BETA; 2,3-BUTANEDIOL PRODUCTION;
D O I
10.1039/d0cy00784f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Butadiene is a crucial chemical, notably for the manufacturing of car tires. The ethanol-to-butadiene reaction has emerged as a promising solution to both environmental concerns and the disruption caused by the emergence of shale gas associated with butadiene production. As a result, it has gathered significant scientific interest and private companies are investigating its application. Although there has been much insight into the reaction and its catalysts in recent years, several issues need to be resolved before becoming financially viable. This review aims to provide up-to-date insight into the ethanol-to-butadiene reaction, including topics that are seldom addressed. It can serve as a starting point for any new research projects on the subject of ethanol conversion to butadiene.
引用
收藏
页码:4860 / 4911
页数:52
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