Separation of Single-Walled Carbon Nanotubes by 1-Dodecanol-Mediated Size-Exclusion Chromatography

被引:112
作者
Flavel, Benjamin S. [1 ]
Kappes, Manfred M. [1 ,2 ]
Krupke, Ralph [1 ,3 ]
Hennrich, Frank [1 ]
机构
[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Inst Phys Chem, D-76128 Karlsruhe, Germany
[3] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
关键词
carbon nanotubes; gel filtration; size-exclusion chromatography; separation; sorting; purification; SODIUM DODECYL-SULFATE; SURFACTANT; GRAPHITE; SUSPENSION;
D O I
10.1021/nn4004956
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, single-column, high-throughput fractionation procedure based on size-exclusion chromatography of aqueous sodium dodecyl sulfate suspensions of single-walled carbon nanotubes (SWCNTs) is presented. This procedure is found to yield monochiral or near monochiral SWCNT fractions of semiconducting SWCNTs. Unsorted and resulting monochiral suspensions are characterized using optical absorption and photoluminescence spectroscopy.
引用
收藏
页码:3557 / 3564
页数:8
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